| 1424002-37-8

• CAS: 1424002-37-8
• 化学式: C₄₈H₄₂Co₂O₆P₂
• 分子量: 894.792
• InChiKey: MBNOQYDSDOHARS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三(邻甲基苯基)磷 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Hydrogenation of α-enaminoketones with cobalt phosphine-modified catalysts

  摘要：

  The synthesis of alpha-enamines and hydrogenation of these compounds were studied using cobalt-modified complexes. Cobalt complexes were characterized by H-1, C-13 and P-31 NMR, elemental analysis and IR spectroscopy. Furthermore, the molecular structures of complexes C1-C2 and C4-C5 have been determined by single-crystal X-ray diffraction. All cobalt complexes investigated were active catalysts for the hydrogenation reaction. The best catalytic activity was obtained with an ortho-substituent in the phosphine ligand. Noteworthy, the reduction was chemoselective over the double bond. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2012.12.025
• 作为试剂：
  描述：

  3,4-己二酮 、 对氯苯胺 在 magnesium(II) perchlorate 、 一氧化碳 、 C₄₈H₄₂Co₂O₆P₂ 、 氢气 、 magnesium sulfate 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 120.0 ℃ 、3.1 MPa 条件下， 反应 30.0h， 生成 4-((4-chlorophenyl)amino)hexan-3-one
  参考文献：
  名称：

  Hydrogenation of α-enaminoketones with cobalt phosphine-modified catalysts

  摘要：

  The synthesis of alpha-enamines and hydrogenation of these compounds were studied using cobalt-modified complexes. Cobalt complexes were characterized by H-1, C-13 and P-31 NMR, elemental analysis and IR spectroscopy. Furthermore, the molecular structures of complexes C1-C2 and C4-C5 have been determined by single-crystal X-ray diffraction. All cobalt complexes investigated were active catalysts for the hydrogenation reaction. The best catalytic activity was obtained with an ortho-substituent in the phosphine ligand. Noteworthy, the reduction was chemoselective over the double bond. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2012.12.025