Pt2(bis(bis(trifluoroethoxy)phosphino)methylamine)2Cl2 | 1100127-05-6

• 英文名称: Pt2(bis(bis(trifluoroethoxy)phosphino)methylamine)2Cl2
• CAS: 1100127-05-6
• 化学式: C₁₈H₂₂Cl₂F₂₄N₂O₈P₄Pt₂
• 分子量: 1435.3
• InChiKey: PVZHRSRQNQRMOL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Pt2(bis(bis(trifluoroethoxy)phosphino)methylamine)2Cl2 、 (二氯碘)-苯 以 not given 为溶剂， 生成 Pt2(bis(bis(trifluoroethoxy)phosphino)methylamine)2Cl4
  参考文献：
  名称：

  Chlorine Photoelimination from a Diplatinum Core: Circumventing the Back Reaction

  摘要：

  The d(9)center dot center dot center dot d(9) Pt-2(I,I)(tfepma)(2)Cl-2 (1) compound (tfepma = ((CF3CH2O)(2)P)(2)NCH3), d(7)-d(9) Pt-2(I,III)(tfepma)(2)Cl-4 (2) and d(7)-d(7) Pt-2(III,III)(tfepma)(2)Cl-6 (3), homologous suite of compounds have been prepared. Irradiation of 3 with visible light generates 2 in solution in the presence of 2,3-dimethyl-1,3-butadiene with a quantum efficiency of similar to 38%. The evolution of Cl-2 upon solid-state phototysis of 3 represents the first example of the thermodynamically unfavorable halogen elimination without the use of a chemical trap.

  DOI：

  10.1021/ja807222p
• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 酰亚胺基二亚磷酸,甲基-,四(2,2,2-三氟乙基)酯 以 not given 为溶剂， 生成 Pt2(bis(bis(trifluoroethoxy)phosphino)methylamine)2Cl2
  参考文献：
  名称：

  Chlorine Photoelimination from a Diplatinum Core: Circumventing the Back Reaction

  摘要：

  The d(9)center dot center dot center dot d(9) Pt-2(I,I)(tfepma)(2)Cl-2 (1) compound (tfepma = ((CF3CH2O)(2)P)(2)NCH3), d(7)-d(9) Pt-2(I,III)(tfepma)(2)Cl-4 (2) and d(7)-d(7) Pt-2(III,III)(tfepma)(2)Cl-6 (3), homologous suite of compounds have been prepared. Irradiation of 3 with visible light generates 2 in solution in the presence of 2,3-dimethyl-1,3-butadiene with a quantum efficiency of similar to 38%. The evolution of Cl-2 upon solid-state phototysis of 3 represents the first example of the thermodynamically unfavorable halogen elimination without the use of a chemical trap.

  DOI：

  10.1021/ja807222p