Mn(CO)2(η5-C5H4CH3)(P(C6H5)2(C6H4OH) | 507225-10-7

• 英文名称: Mn(CO)2(η5-C5H4CH3)(P(C6H5)2(C6H4OH)
• CAS: 507225-10-7
• 化学式: C₂₆H₂₂MnO₃P
• 分子量: 468.371
• InChiKey: ZYZOCHBOMSCIFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  六氯环三磷腈 、 Mn(CO)2(η5-C5H4CH3)(P(C6H5)2(C6H4OH) 在 caesium carbonate 作用下， 以 四氢呋喃 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Synthesis and spectroscopic characterization of cyclic and polymeric phosphazenes bearing phosphine complexes

  摘要：

  The reactions of the cyclic phosphazenes [N3P3Cl6] and [N3P3(O2Cl2H8)(2)Cl-2] (O2Cl2H8 = 2,2'-dioxybiphenyl) with the diphenylphosphine phenol complex {Mn(CO)(2)(eta(5)-C5H4Me)[PPh2(C6H4-OH)]} (1) and Cs2CO3 in refluxing acetone gave, respectively the phosphazenc-phosphine complexes {N3P3[OC6H4PPh2-Mn(CO)(2)(eta(5)-C5H4Me)](6)} (2) and {N3P3(o(2)Cl(2)H(8))(2)[OC6H4PPh2-Mn(CO)(2)(eta(5)-C5H4Me)](2)} (3). in good yields. The analogous reaction of the partially substituted clorophosphazene polymer {[NP(O2Cl2H8)](0.6)[NPCl2](0.4)}(n) in THF gave the polymeric complex [{NP(O2Cl2H8)}(0.6){NP[OC6H4PPh2-Mn(CO)(2)(eta(5)- C5H4Me)](2)}(0.4)-0.5[OC4H8](n) (4). Different spectroscopic data are provided for the new compounds that may be useful for the characterization of other more complex polymeric materials. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01233-0
• 作为产物：
  描述：

  methylcyclopentadienyl manganese(I) tricarbonyl 、 (4-羟基苯基)二苯基膦 以 四氢呋喃 为溶剂， 以71%的产率得到Mn(CO)2(η5-C5H4CH3)(P(C6H5)2(C6H4OH)
  参考文献：
  名称：

  Synthesis and spectroscopic characterization of cyclic and polymeric phosphazenes bearing phosphine complexes

  摘要：

  The reactions of the cyclic phosphazenes [N3P3Cl6] and [N3P3(O2Cl2H8)(2)Cl-2] (O2Cl2H8 = 2,2'-dioxybiphenyl) with the diphenylphosphine phenol complex {Mn(CO)(2)(eta(5)-C5H4Me)[PPh2(C6H4-OH)]} (1) and Cs2CO3 in refluxing acetone gave, respectively the phosphazenc-phosphine complexes {N3P3[OC6H4PPh2-Mn(CO)(2)(eta(5)-C5H4Me)](6)} (2) and {N3P3(o(2)Cl(2)H(8))(2)[OC6H4PPh2-Mn(CO)(2)(eta(5)-C5H4Me)](2)} (3). in good yields. The analogous reaction of the partially substituted clorophosphazene polymer {[NP(O2Cl2H8)](0.6)[NPCl2](0.4)}(n) in THF gave the polymeric complex [{NP(O2Cl2H8)}(0.6){NP[OC6H4PPh2-Mn(CO)(2)(eta(5)- C5H4Me)](2)}(0.4)-0.5[OC4H8](n) (4). Different spectroscopic data are provided for the new compounds that may be useful for the characterization of other more complex polymeric materials. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01233-0