| 649760-61-2

• CAS: 649760-61-2
• 化学式: C₁₄H₁₉ClMoNO₃P
• 分子量: 411.677
• InChiKey: NCMBROOJATWDPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  羰基镁 、 以 二氯甲烷 为溶剂， 生成 [CpMoMn(CO)6(μ-PNiPr2)]
  参考文献：
  名称：

  The reactivity of terminal chloroaminophosphido ligands towards metal carbonyl complexes. Formation of μ2- and μ3-phosphinidene clusters

  摘要：

  Reactions of the terminal molybdenum phosphido compounds [CpMo(CO)(2){P(Cl)TMP}] (1, TMP = 2,2,6,6-tetramethyl-1-piperidyl) and [Cp*Mo(CO)(3){P(Cl)(NPr2)-Pr-i}] (3) with Co-2(CO)(8) lead to the heterobimetallic phosphinidene bridged compounds [CpMoCo(CO)(5){mu-P(TMP)}] (4a) and [Cp*MoCo(CO)(5){mu-P((NPr2)-Pr-i)}] (4b). Under photolysis, 1 and [CpMo(CO)(3){P(Cl)(NPr2)-Pr-i}] (2) react with Mn-2(CO)(10) and [CpMo(CO)(3)](2) to form the hetero- and homo-bimetallic phosphinidene bridged complexes [CpMoMn(CO)(6)(mu-PNR2)] (5a, NR2 = TMP; b, NR2 = (NPr2)-Pr-i) and [{CpMo(CO)(2)}(2){mu-PNR2}] (6a, b). Thermolysis of 1 with Ru-3(CO)(12) leads to the heterotrimetallic cluster [CpMoRu2(CO)(8)(mu-H){mu(3)-P(TMP)}] (7a), while thermolysis of 2 with Ru-3(CO)(12) leads to [CpMoRu2(CO)(8)(mu-H)(mu(3)-(PNPr2)-Pr-i)] (7b) and the ruthenium clusters [Ru-5(CO)(15){mu(4)-(PNPr2)-Pr-i}] (8), [Ru-3(CO)(9)(mu-H)(2)(mu(3)-(PNPr2)-Pr-i)] (9), and [Ru-3(CO)(9)(mu(3)-(PNPr2)-Pr-i)(2)] (10) (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01558-x
• 作为产物：
  描述：

  Na[Mo(CO)3(cyclopentadienyl)] 、 二氯-N,N-二异丙基亚磷酰胺 以 四氢呋喃 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  The reactivity of terminal chloroaminophosphido ligands towards metal carbonyl complexes. Formation of μ2- and μ3-phosphinidene clusters

  摘要：

  Reactions of the terminal molybdenum phosphido compounds [CpMo(CO)(2){P(Cl)TMP}] (1, TMP = 2,2,6,6-tetramethyl-1-piperidyl) and [Cp*Mo(CO)(3){P(Cl)(NPr2)-Pr-i}] (3) with Co-2(CO)(8) lead to the heterobimetallic phosphinidene bridged compounds [CpMoCo(CO)(5){mu-P(TMP)}] (4a) and [Cp*MoCo(CO)(5){mu-P((NPr2)-Pr-i)}] (4b). Under photolysis, 1 and [CpMo(CO)(3){P(Cl)(NPr2)-Pr-i}] (2) react with Mn-2(CO)(10) and [CpMo(CO)(3)](2) to form the hetero- and homo-bimetallic phosphinidene bridged complexes [CpMoMn(CO)(6)(mu-PNR2)] (5a, NR2 = TMP; b, NR2 = (NPr2)-Pr-i) and [{CpMo(CO)(2)}(2){mu-PNR2}] (6a, b). Thermolysis of 1 with Ru-3(CO)(12) leads to the heterotrimetallic cluster [CpMoRu2(CO)(8)(mu-H){mu(3)-P(TMP)}] (7a), while thermolysis of 2 with Ru-3(CO)(12) leads to [CpMoRu2(CO)(8)(mu-H)(mu(3)-(PNPr2)-Pr-i)] (7b) and the ruthenium clusters [Ru-5(CO)(15){mu(4)-(PNPr2)-Pr-i}] (8), [Ru-3(CO)(9)(mu-H)(2)(mu(3)-(PNPr2)-Pr-i)] (9), and [Ru-3(CO)(9)(mu(3)-(PNPr2)-Pr-i)(2)] (10) (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01558-x