| 1600504-63-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1600504-63-9
• 化学式: C₂₃H₃₄Cl₂NO₉
• 分子量: 539.43
• InChiKey: RSCGLVXXIAEOMV-YQGCTJEISA-N

反应信息

• 作为产物：
  描述：

  heptamethyl-6'-[α-D-galactopyranoside, 1'-chloro-1',6'-dideoxy-β-D-fructofuranosyl-4-chloro-4-deoxy]cobyrinate perchlorate 在 N-叔丁基-α-苯基硝酮 作用下， 生成
  参考文献：
  名称：

  Alkylcobyrinate from sucralose and mechanistic aspects of its CoC bond cleavage

  摘要：

  Reaction of heptamethyl cob(I)yrinate with 1',6'-dichloro-1',6'-dideoxy-beta-D-fructofuranosyl-4-chloro-4-deoxy-alpha-D-galactopyranoside (sucralose) gave an alkylcobyrinate, heptamethyl-6'-[alpha-D-galactopyranoside- 1'-chloro-1',6'-dideoxy-beta-D-fructofuranosyl-4-chloro-4-deoxy]cobyrinate perchlorate, [(Suc)Cob(III) 7C(1)ester]ClO4. Cleavage behavior of Co-C bond of the alkylcobyrinate was investigated under various conditions (hv, H+ and reduction) using UV-vis spectroscopy combined with the EPR spin-trapping technique, and by cyclic voltammetry. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.03.028