| 260353-48-8

• CAS: 260353-48-8
• 化学式: C₂₉H₂₆O₉Re₂
• 分子量: 890.934
• InChiKey: BQCAZVWDZBMETR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四溴化碳 、 在 PPh₃ 作用下， 以 四氢呋喃 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of a first generation organorhenium dendrimer

  摘要：

  A new, more efficient route to the functionalized Cp compound [eta(5)-(C5H4)CH2CH2CH2I]Re(CO)(3), (2) is reported. The reaction of 2 with [(LiC5H4)Re(CO)(3)] yields the new binuclear complex (CO)(3)Re[(eta(5)-C5H4)(CH2)(3)(eta(5)-C5H4]Re(CO)(3)). The crystal structure of 3 has been determined. Crystals of 3 are triclinic, space group P (1) over bar, with a = 8.241(1) Angstrom, b = 11.154(1) Angstrom, c = 11.699(1) Angstrom, alpha = 106.383(10)degrees, beta = 102.512(10)degrees, gamma = 105.067(10)degrees, Z = 2 and R = 0.045. Compound 2 has also been used to build up a first generation organometallic dendrimer containing six rhenium units by the convergent method. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00543-4
• 作为产物：
  描述：

  [(η5-C5H4)(CH2)3I]Re(CO)3 、 3,5-二羟基苯甲醇 在 K₂CO₃ 、 18-crown-6 作用下， 以 丙酮 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of a first generation organorhenium dendrimer

  摘要：

  A new, more efficient route to the functionalized Cp compound [eta(5)-(C5H4)CH2CH2CH2I]Re(CO)(3), (2) is reported. The reaction of 2 with [(LiC5H4)Re(CO)(3)] yields the new binuclear complex (CO)(3)Re[(eta(5)-C5H4)(CH2)(3)(eta(5)-C5H4]Re(CO)(3)). The crystal structure of 3 has been determined. Crystals of 3 are triclinic, space group P (1) over bar, with a = 8.241(1) Angstrom, b = 11.154(1) Angstrom, c = 11.699(1) Angstrom, alpha = 106.383(10)degrees, beta = 102.512(10)degrees, gamma = 105.067(10)degrees, Z = 2 and R = 0.045. Compound 2 has also been used to build up a first generation organometallic dendrimer containing six rhenium units by the convergent method. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00543-4