[Ru(bpy)(tpy)(Ipcyd)]PF6 | 352020-07-6

• 英文名称: [Ru(bpy)(tpy)(Ipcyd)]PF6
• 英文别名: [Ru(2,2'-bipyridine)(2,2':6',2''-terpyridine)(4-iodophenylcyanamide)] hexafluorophosphate；(bipyridine)(terpyridine)(4-iodophenylcyanamide)ruthenium(II) hexafluorophosphate
• CAS: 352020-07-6
• 化学式: C₃₂H₂₃IN₇Ru*F₆P
• 分子量: 878.52
• InChiKey: SZXQHBDQCORHBW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(bpy)(tpy)(Ipcyd)]PF6 、 1,4-二乙炔基苯 在 catalyst:CuI / [PdCl₂(PPh₃)2] 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以89%的产率得到[[Ru(bpy)(tpy)]2(μ-dcpeb)](PF6)2
  参考文献：
  名称：

  X-ray Structure of a Ruthenium Dinuclear Complex Incorporating 4,4′-Bis(cyanamidophenylethynyl)benzene as a Ligand, a Conjugated Bridge Two Nanometers in Length

  摘要：

  DOI：

  10.1002/1099-0682(200208)2002:8<1924::aid-ejic1924>3.0.co;2-y
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 六氟磷酸银 、 2,2'-bipyridine(2,2':6',2''-terpyridine)chlororuthenium(II) hexafluorophosphate 、 N-(4-iodophenyl)cyanamide 以 丙酮 为溶剂， 以78%的产率得到[Ru(bpy)(tpy)(Ipcyd)]PF6
  参考文献：
  名称：

  (Bipyridine)(terpyridine)(4-iodophenylcyanamide)ruthenium(II) complex: crystallography, electronic absorption spectroscopy, cyclic voltammetry and EPR measurements

  摘要：

  The complex [Ru(bpy)(tpy)(Ipcyd)](+) (where bpy: 2,2'-bipyridine, tpy: 2,2':6',2 " -terpyridine and Ipcyd: 4-iodophenyloyanamide anion) has been synthesized. An extensive characterization was carried out using IR, H-1 and C-13 NMR, ES-MS, UV-Vis, electrochemistry, EPR and X-ray single crystal diffraction analysis. Cyclic voltammogram shows an irreversible anodic peak around 0.7 V/ECS, the shape of the wave is typical of an electrochemical-chemical (EC) mechanism with an half-life time in the order of seconds for the generated species. Oxidation of the title compound has been investigated in order to explore its ability as a magnetic probe for further electronic studies on dinuclear complexes. The EPR spectrum at 100 K of the monooxidized species displays g(perpendicular to) = 2.00 and g(parallel to) = 1.96 attributed to the presence of a radical coming from the phenylcyanamide oxidation, in relative good agreement with EH and ZINDO calculations. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00382-6