[(C(C(NiPr)2))(ZnH)4] | 1254831-54-3

• 英文名称: [(C(C(NiPr)2))(ZnH)4]
• CAS: 1254831-54-3
• 化学式: C₂₉H₆₀N₈Zn₄
• 分子量: 782.409
• InChiKey: FCNKGGJIKPMXQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(C(C(NiPr)2))(ZnH)4] 、 苯乙炔 以 四氢呋喃 为溶剂， 以81%的产率得到[(C(C(NiPr)2))(Zn(phenylacetylenide))4]
  参考文献：
  名称：

  Synthesis, Structure, and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex

  摘要：

  The tetranuclear amidinato zinc hydride complex {C[C(Ni-Pr)(2)ZnH)(4)} (3) was synthesized by reaction of the Cl-substituted complex (C[C(Ni-Pr)(2)ZnCl](4)} with CaH2. 3 was found to react with phenylacetylene and acetylene at ambient temperature with elimination of H-2 and subsequent formation of C[C(Ni-Pr)(2)ZnC CPh](4) (4) and (C[C(Ni-Pr)(2)-ZnC CH](4) (5), respectively. 3-5 have been characterized by multinuclear NMR (H-1, C-13) and IR spectroscopy, elemental analyses, and single-crystal X-ray diffraction.

  DOI：

  10.1021/om100966d
• 作为产物：
  描述：

  calcium hydride 、 [(C(C(NiPr)2))(ZnCl)4] 以 四氢呋喃 为溶剂， 以91%的产率得到[(C(C(NiPr)2))(ZnH)4]
  参考文献：
  名称：

  Synthesis, Structure, and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex

  摘要：

  The tetranuclear amidinato zinc hydride complex {C[C(Ni-Pr)(2)ZnH)(4)} (3) was synthesized by reaction of the Cl-substituted complex (C[C(Ni-Pr)(2)ZnCl](4)} with CaH2. 3 was found to react with phenylacetylene and acetylene at ambient temperature with elimination of H-2 and subsequent formation of C[C(Ni-Pr)(2)ZnC CPh](4) (4) and (C[C(Ni-Pr)(2)-ZnC CH](4) (5), respectively. 3-5 have been characterized by multinuclear NMR (H-1, C-13) and IR spectroscopy, elemental analyses, and single-crystal X-ray diffraction.

  DOI：

  10.1021/om100966d