cis-[(5-(4-dimethylaminobenzylidene)rhodanine)tetra-carbonylchromate(0)] | 1123204-07-8

• 英文名称: cis-[(5-(4-dimethylaminobenzylidene)rhodanine)tetra-carbonylchromate(0)]
• CAS: 1123204-07-8
• 化学式: C₁₆H₁₂CrN₂O₅S₂
• 分子量: 428.41
• InChiKey: YLANCBGIWUTZQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetracarbonylnorbornadienchrom 、 对二甲氨基苄罗丹宁 以 四氢呋喃 为溶剂， 以62%的产率得到cis-[(5-(4-dimethylaminobenzylidene)rhodanine)tetra-carbonylchromate(0)]
  参考文献：
  名称：

  Photochemical reactions of cis-[(η4-NBD)M(CO)4] (NBD = norbornadiene; M = Cr, Mo) olefin complex with ligand, containing S and N donor atoms

  摘要：

  New complexes cis-[M(CO)(4)-DABRd] (M = Cr(I), Mo(II) and fac-[M(CO)(3)-SAT] (M = Cr(III), Mo(IV)) have been synthesized by the photochemical reactions of cis-[(eta(4)-NBD)M(CO)(4)] (NBD = norbornadiene; M = Cr, Mo) with 5-(4-dimethylaminobenzylidene) rhodanine (DABRd) and saticylidene-3-amino1,2,4-triazole (SAT) ligands and characterized by elemental analysis, FT-IR and H-1 NMR spectroscopy, and mass spectrometry. The spectroscopic studies show that the DABRd ligand acts as a bidentate ligand coordinating via both NH-(S)C=S sulfur donor atoms in I and II and SAT ligand behaves as a tridentate ligand coordinating via its all imine nitrogen -C=N- donor atoms in III and IV to the metal center.

  DOI：

  10.1134/s1070328407120032