[σ-methyltriethoxysilane-η5-cyclopentadienyl]tricarbonyl molybdenum | 871736-70-8

• 英文名称: [σ-methyltriethoxysilane-η5-cyclopentadienyl]tricarbonyl molybdenum
• CAS: 871736-70-8
• 化学式: C₁₅H₂₂MoO₆Si
• 分子量: 422.362
• InChiKey: MEQRYQBACIFPSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Na[Mo(CO)3(cyclopentadienyl)] 、 (iodomethyl)triethoxysilane 以 四氢呋喃 为溶剂， 以47%的产率得到[σ-methyltriethoxysilane-η5-cyclopentadienyl]tricarbonyl molybdenum
  参考文献：
  名称：

  Siloxane functionalized cyclopentadienyl-molybdenum complexes: Synthesis, characterization and catalytic application

  摘要：

  A series of compounds of the type CpMoR(CO)(3) and RCPMO(CO)(3)CH3 (R = (CH2)(3)Si(OMe)(3) or CH2Si(OEt)(3)) containing a (CH2),Si(OR)3 functionality as a side chain, either fixed to the metal itself or to the cyclopentadienyl ligand are prepared and spectroscopicatly characterized. These molecules are applicable as precursors for both homogeneous and heterogeneous phase catalysts. Their homogeneous catalytic activity in the olefin epoxidation is in the same order of magnitude as that of their methyl and chloro analogues of the types CpMp(CO)(3)R and CPMO(CO)(3)Cl. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.03.004