Cu(PMDT)(OAc)PF6 | 932739-73-6

• 英文名称: Cu(PMDT)(OAc)PF6
• 英文别名: Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)(OAc)PF6
• CAS: 932739-73-6
• 化学式: C₁₁H₂₆CuN₃O₂*F₆P
• 分子量: 440.857
• InChiKey: XDUPVCJHXCUEEB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium hexaflorophosphate 、 五甲基二乙烯三胺 、 copper(II) acetate monohydrate 以 甲醇 、 水 为溶剂， 以80%的产率得到Cu(PMDT)(OAc)PF6
  参考文献：
  名称：

  Copper(II) complexes of tridentate N,N,N′,N″,N″-pentamethyldiethylenetriamine: Superoxide dismutase and inhibitory activity against bacteria and fungi

  摘要：

  A series of ternary copper(II) complexes containing same coordination sphere but difference in the counter ions, viz., [Cu(PMDT)(OAc)]PF6 (1); [Cu(PMDT)(OAc)]ClO4 (2); [Cu(PMDT)(OAc)]BF4 (3) and [Cu(PMDT)(OAc)]BPh4 (4) where PMDT=N,N,N',N'',N''-pentamethyldiethylenetriamine, OAc=Acetate ion were synthesized and characterized by means of spectroscopic, magnetic and cyclic voltammetric measurements. In frozen solution e.p.r. spectra, an interesting relation g(parallel to) > g(perpendicular to) has been observed which is a typical of the axially symmetric d(9) Cu-II (S-Cu = 1/2) having an unpaired electron in a d(x2-y2) orbital. Single crystal X-ray analysis of (1) has revealed the presence of distorted square planar geometry. The influence of the counter ion on the complexes has been examined by performing some biological experiments like superoxide dismutase and anti-microbial activity. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2006.04.017