citric acid methacrylate | 334886-99-6

• 英文名称: citric acid methacrylate
• 英文别名: 2-(2-Methylprop-2-enoyloxy)propane-1,2,3-tricarboxylic acid
• CAS: 334886-99-6
• 化学式: C₁₀H₁₂O₈
• 分子量: 260.2
• InChiKey: BFABTDLHJZNAAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  138
• 氢给体数：
  3
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2,2,2-三氟乙醇 、 citric acid methacrylate 在 N,N-二甲基甲酰胺 草酰氯 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 7.0h， 以40%的产率得到Tris(2,2,2-trifluoroethyl) 2-(2-methylprop-2-enoyloxy)propane-1,2,3-tricarboxylate
  参考文献：
  名称：

  RADIATION SENSITIVE RESIN COMPOSITION, METHOD FOR FORMING A PATTERN, POLYMER AND COMPOUND

  摘要：

  一种辐射敏感性树脂组合物，包括具有下式（1）所代表的基团的第一聚合物和辐射敏感性酸发生剂。n是2到4的整数。X代表单键或二价有机基团。A代表（n+1）价的连接基团。每个Q独立地代表包括可溶于碱的基团的基团。

  公开号：

  US20120276482A1
• 作为产物：
  描述：

  Triethyl 2-(2-methylprop-2-enoyloxy)propane-1,2,3-tricarboxylate 在 lithium hydroxide 作用下， 以 甲醇 、 水 为溶剂， 反应 1.0h， 以60%的产率得到citric acid methacrylate
  参考文献：
  名称：

  RADIATION SENSITIVE RESIN COMPOSITION, METHOD FOR FORMING A PATTERN, POLYMER AND COMPOUND

  摘要：

  一种辐射敏感性树脂组合物，包括具有下式（1）所代表的基团的第一聚合物和辐射敏感性酸发生剂。n是2到4的整数。X代表单键或二价有机基团。A代表（n+1）价的连接基团。每个Q独立地代表包括可溶于碱的基团的基团。

  公开号：

  US20120276482A1

文献信息

• Monomers, Polymers, Dispersions and Inks
  申请人：LOZMAN Owen Roger

  公开号：US20110040026A1

  公开（公告）日：2011-02-17

  A compound of Formula (1) or a salt thereof: wherein R is H, methyl or ethyl.

  化合物的化学式（1）或其盐：其中R为H、甲基或乙基。
• RADICAL-CURABLE ADHESIVE COMPOSITION AND POLARIZING PLATE COMPRISING SAME
  申请人：LG Chem, Ltd.

  公开号：EP2840124A1

  公开（公告）日：2015-02-25

  There are provided a radically curable adhesive composition and a polarizing plate including the radically curable adhesive composition. The radically curable adhesive composition includes, based on 100 parts by weight thereof, 40 to 80 parts by weight of a first compound represented by the following Formula 1; 15 to 50 parts by weight of a second compound including at least one carboxy group; and 0.5 to 10 parts by weight of a radical initiator.

  提供了一种可辐射固化的粘合剂组合物和一种包括该可辐射固化的粘合剂组合物的偏光板。该辐射固化粘合剂组合物以 100 份重量计，包括 40 至 80 份重量的由下式 1 表示的第一种化合物；15 至 50 份重量的包括至少一个羧基的第二种化合物；以及 0.5 至 10 份重量的自由基引发剂。
• Radical curable adhesive composition and polarizing plate comprising same
  申请人：LG CHEM, LTD.

  公开号：US10011746B2

  公开（公告）日：2018-07-03

  The present invention relates to a radical-curable adhesive composition including a first compound represented by [Chemical Formula I]; a radical-curable second compound including at least one carboxyl group conjugated with a carbon-carbon unsaturated double bond present in the side chain in the molecule; and a radical initiator, and a polarizing plate including the radical-curable adhesive composition.

  本发明涉及一种自由基固化粘合剂组合物，包括由[化学式 I]表示的第一种化合物；自由基固化第二种化合物，包括至少一个与分子中侧链上存在的碳-碳不饱和双键共轭的羧基；自由基引发剂，以及包括该自由基固化粘合剂组合物的偏光板。
• RADICALLY CURABLE ADHESIVE COMPOSITION AND POLARIZING PLATE INCLUDING THE SAME
  申请人：LG CHEM, LTD.

  公开号：US20160244644A1

  公开（公告）日：2016-08-25

  There are provided a radically curable adhesive composition and a polarizing plate including the radically curable adhesive composition. The radically curable adhesive composition includes, based on 100 parts by weight thereof, 40 to 80 parts by weight of a first compound represented by the following Formula 1; 15 to 50 parts by weight of a second compound including at least one carboxy group; and 0.5 to 10 parts by weight of a radical initiator.
• POLARIZING PLATE
  申请人：LG CHEM, LTD.

  公开号：US20160238745A1

  公开（公告）日：2016-08-18

  The present disclosure relates to a polarizing plate excellent durability even under high humidity conditions and more particularly, to a polarizing plate including a polarizer and a protective layer formed on at least one surface of the polarizer, wherein the protective layer is formed of a cured product of a radically curable composition including a compound represented by the following [Chemical Formula 1]; a vinyl ether compound; a carboxylic acid compound including at least one unsaturated double bond; and a radical initiator.