5-ruthenocenylbenzaldehyde | 1007403-82-8

• 英文名称: 5-ruthenocenylbenzaldehyde
• CAS: 1007403-82-8
• 化学式: C₁₇H₁₄ORu
• 分子量: 335.368
• InChiKey: SSTXMRJLDLWHCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  5-ruthenocenylbenzaldehyde 、 ruthenoceny(triphenyl)phosphonium bromide 、 苯 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 生成 [4-(2'-ruthenocenyl-E-ethenyl)-1-ruthenocenylbenzene]*0.5C6H6
  参考文献：
  名称：

  Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives

  摘要：

  Binuclear ruthenocenes bridged by ethenes and thiophene derivatives, Rc-CH=CH-Z-Rc and Rc*-CH=CH-Z CH=CH-Rc* (Z = thiophene, thieno[3,2-b]thiophene, and 2,2'-bithiophene; Rc = ruthenocenyl, R* = 1',2',3',4',5'-pentamethylruthenocenyl) were prepared. These complexes showed a one-step two-electron redox wave in the cyclic voltammograms, in contrast to the benzenoid-bridged dinuclear ruthenocenes. The chemical oxidation of the Rc-CH=CH-Z-Rc complexes gave no stable oxidized species. The two-electron oxidized species of the Rc*-CH=CH-Z-CH=CH-Rc* complexes were comparably stable and contained a fulvene-complex type structure. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.057
• 作为产物：
  描述：

  2-ruthenocenyl-4,4,5,5-tetramethyl-1,3-dioxa-2-borolane 、 对溴苯甲醛 在 四(三苯基膦)钯 sodium hydroxide 作用下， 以 乙二醇二甲醚 、 水 为溶剂， 以29%的产率得到5-ruthenocenylbenzaldehyde
  参考文献：
  名称：

  Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives

  摘要：

  Binuclear ruthenocenes bridged by ethenes and thiophene derivatives, Rc-CH=CH-Z-Rc and Rc*-CH=CH-Z CH=CH-Rc* (Z = thiophene, thieno[3,2-b]thiophene, and 2,2'-bithiophene; Rc = ruthenocenyl, R* = 1',2',3',4',5'-pentamethylruthenocenyl) were prepared. These complexes showed a one-step two-electron redox wave in the cyclic voltammograms, in contrast to the benzenoid-bridged dinuclear ruthenocenes. The chemical oxidation of the Rc-CH=CH-Z-Rc complexes gave no stable oxidized species. The two-electron oxidized species of the Rc*-CH=CH-Z-CH=CH-Rc* complexes were comparably stable and contained a fulvene-complex type structure. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.057