| 618382-20-0

• CAS: 618382-20-0
• 化学式: C₄H₁₆CuN₄*C₁₂H₁₈Cd₂O₁₂
• 分子量: 762.832
• InChiKey: FGIDJTCHJYNPGH-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙酸铵 、 铜 、 乙二胺 、 cadmium(II) oxide 在 O₂ 作用下， 以 甲醇 为溶剂， 以62.5%的产率得到
  参考文献：
  名称：

  Novel heterometallic Cu/Cd complex containing a unique polymeric ladder-like anion [Cd2(O2CMe)6]2−n derived from elemental copper and cadmium oxide

  摘要：

  Copper powder reacts with cadmium oxide and ammonia acetate in methanol solution of ethylenediamine affording {[Cu(en)(2)][Cd-2(O2CMe)(6)]}(n) in which seven-coordinated cadmium atoms are ligated by three bonding modes of acetate groups forming ladder-like anions [Cd-2(O2CMe)(6)](n)(2-). The cations [Cu(en)(2)](2+) are located in the lattice and serve as bridges to connect separate anionic polymer chains into a two- dimensional network via hydrogen bonds. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00138-2