[Ru(1,4,7-trimethyl-1,4,7-triazacyclononane)(1,2-bis(diphenylphosphino)ethane)Cl]O3SCF3 | 169621-96-9

• 英文名称: [Ru(1,4,7-trimethyl-1,4,7-triazacyclononane)(1,2-bis(diphenylphosphino)ethane)Cl]O3SCF3
• CAS: 169621-96-9
• 化学式: CF₃O₃S*C₃₅H₄₅ClN₃P₂Ru
• 分子量: 855.303
• InChiKey: ZYFHKAOHSOBIPO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三甲基氯硅烷 、 Ru(1,4,7-trimethyl-1,4,7-triazacyclononane)Cl3 、 silver trifluoromethanesulfonate 、 锌 在 Ph₂PCH₂CH₂PPh₂ 作用下， 以 四氢呋喃 为溶剂， 以44%的产率得到[Ru(1,4,7-trimethyl-1,4,7-triazacyclononane)(1,2-bis(diphenylphosphino)ethane)Cl]O3SCF3
  参考文献：
  名称：

  Synthesis, characterization and crystal structures of some half-sandwich ruthenium(II) complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane containing π-acidic ancillary ligands

  摘要：

  The synthesis of a series of ruthenium(II) complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane L of type [RuL(X)Y(Z)](+) containing H, O2CCF3, CO, PPh(3), dppe [1,2-bis(diphenylphosphino)ethane] or 2,6-Me(2)C(6)H(3)N=C as auxiliary ligands are described where X = Y = CO, Z = Cl 1; X, Y = dppe, Z = Cl 2; X, Y = dppe, Z = H 3; X = CO, Y = PPh(3), Z = H 4; X = Y = 2.6-Me(2)C(6)H(3)N=C, Z = O2CCF3 5. All complexes were characterized by spectroscopic methods. The crystal structures of 1 and 4 as PF6- salts have been determined. The two CO groups in complex 1 are in cis-fashion with a OC-Ru-CO angle of 90.1(3)degrees and the RU-C distances are 1.850(6) and 1.893(6) Angstrom. Complex 4 features one of the few ruthenium: complexes containing three different piano-stool ligands, namely. CO, PPh(3) and H. The measured RU-CO and Ru-H distances in 4 are 1.785(9) and 1.54(9) Angstrom respectively.

  DOI：

  10.1039/dt9950002955