(iPrNHPPh2)Mo(CO)5 | 85762-10-3

• 英文名称: (iPrNHPPh2)Mo(CO)5
• 英文别名: (ⁱPrNHPPh₂)Mo(CO)₅
• CAS: 85762-10-3
• 化学式: C₂₀H₁₈MoNO₅P
• 分子量: 479.28
• InChiKey: JLADQNJXCBLFRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (chlorodiphenylphosphine)pentacarbonylmolybdenum(0) 、 异丙胺 以 四氢呋喃 为溶剂， 以46%的产率得到(iPrNHPPh2)Mo(CO)5
  参考文献：
  名称：

  Gray, Gary M.; Gray, Rita June, Organometallics, 1983, vol. 2, # 8, p. 1026 - 1031

  摘要：

  DOI：

文献信息

• Probing substituent effects in phosphinoamine ligands using Mo(CO)5L complexes
  作者：Kyle H. Lee、J.W. Napoline、Mark W. Bezpalko、Bruce M. Foxman、Christine M. Thomas

  DOI：10.1016/j.poly.2014.12.005

  日期：2015.2

  Recent work has revealed substantial differences in the structure, spectroscopic properties, and reactivity of heterobimetallic Zr/Co complexes of the general form XZr(R'NPR2)(3)CoY (R' = Pr-i. 2,4,6-trimethylphenyl, 3,5-dimethylphenyl; R = Ph. Pr-i; X, Y = halides or neutral donor ligands) as a function of nitrogen and phosphorus donor atom substituents. To probe the electronic differences between these ligands, a series of Mo(CO)(5)(R2PNHR') complexes has been synthesized (R = Ph, R' = Pr-i (2a); R = Pr-i, R' = Pr-i (2b), 2,4,6-trimethylphenyl (2c), 3,5-dimethylphenyl (2d), 4-methylphenyl (2e), 4-trifluoromethylphenyl (2f), 4-methoxyphenyl (2g)). Thermolysis of Mo(CO)(6) with the corresponding phosphinoamine ligands 1a-1g affords 2a-2g. The infrared carbonyl stretching frequencies of these complexes have been compared to probe the effects of phosphorus and nitrogen substituents on the electronic properties of the phosphinoamine ligands. (C) 2014 Elsevier Ltd. All rights reserved.