Cl(CO)(triphenylphosphite)3Mo*CBu | 227608-69-7

• 英文名称: Cl(CO)(triphenylphosphite)3Mo*CBu
• CAS: 227608-69-7
• 化学式: C₆₀H₅₄ClMoO₁₀P₃
• 分子量: 1159.4
• InChiKey: DXXBHFSNYIUDAK-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  Cl(CO)2(triphenylphosphite)2Mo*CBu 、 Cl(CO)(triphenylphosphite)3Mo*CBu 、 sodium cyclopentadienide 以 四氢呋喃 为溶剂， 生成 Cp(CO)(triphenylphosphite)Mo*CBu
  参考文献：
  名称：

  Effect of Ligand Variation on the Site of Protonation in the Metal Carbynes CpL₂Mo⋮CBu and TpL₂Mo⋮CBu [L = CO, P(OR)₃]

  摘要：

  The site of thermodynamic protonation of the Fischer carbynes CpL2Mo=CBu and TpL(2)Mo=CBu [L = CO, P(OR)(3)] with HBF4 depends on the number of pi-acid CO ligands. As the number of carbonyls increases from zero to two and the electron density at the metal center is decreased by back-bonding, the protonation site shifts from the metal to the carbyne carbon. Parallel behavior in the Tp and Cp series of complexes allows the change in protonation site to be attributed to electronic effects in the ancillary ligands.

  DOI：

  10.1021/om990047x
• 作为产物：
  描述：

  吡啶 、 正丁基锂 、 草酰氯 、 molybdenum hexacarbonyl 以 乙醚 、 正己烷 、 二氯甲烷 为溶剂， 以90.6%的产率得到Cl(pyridine)2(CO)2Mo*CBu
  参考文献：
  名称：

  Effect of Ligand Variation on the Site of Protonation in the Metal Carbynes CpL₂Mo⋮CBu and TpL₂Mo⋮CBu [L = CO, P(OR)₃]

  摘要：

  The site of thermodynamic protonation of the Fischer carbynes CpL2Mo=CBu and TpL(2)Mo=CBu [L = CO, P(OR)(3)] with HBF4 depends on the number of pi-acid CO ligands. As the number of carbonyls increases from zero to two and the electron density at the metal center is decreased by back-bonding, the protonation site shifts from the metal to the carbyne carbon. Parallel behavior in the Tp and Cp series of complexes allows the change in protonation site to be attributed to electronic effects in the ancillary ligands.

  DOI：

  10.1021/om990047x