[(3,7-bis(2-aminoethyl)-1,3,5,7-tetraazabicyclo[3.3.1]nonane)nickel(II)] tetrabromozincate(II) | 867347-39-5

• 英文名称: [(3,7-bis(2-aminoethyl)-1,3,5,7-tetraazabicyclo[3.3.1]nonane)nickel(II)] tetrabromozincate(II)
• CAS: 867347-39-5
• 化学式: Br₄Zn*C₉H₂₂N₆Ni
• 分子量: 658.01
• InChiKey: UQVLBMODHQWNPP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  formyl radical 、 ethylenediamine dihydrobromide 、 镍 、 丙酮 、 zinc(II) oxide 在 NH₄Br 作用下， 以 二甲基亚砜 、 丙酮 为溶剂， 以45%的产率得到[(3,7-bis(2-aminoethyl)-1,3,5,7-tetraazabicyclo[3.3.1]nonane)nickel(II)] tetrabromozincate(II)
  参考文献：
  名称：

  Heterobimetallic M/Zn (M=Cu, Ni) complexes with open-chain N- and N,O-ligands: Template synthesis from metal powders and supramolecular crystal structures

  摘要：

  A series of new heterometallic (CuZnII)-Zn-II and (NiZnII)-Zn-II complexes with N- and N,O open-chain multidentate ligands (L-1 = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-ene; L-2 = 3,7-bis(2-aminoethyl)-1,3,5,7-tetraazabicyclo[3.3.1]nonane; L-3 = 1, 15-dihydroxy-7,9,9-trimethyl-3,6,10,13-tetraazapentadec-6-ene and L-4 = 1-hydroxy-9-oxy-4,6,6-trimethyl-3,7-diazanon-3-ene) have been prepared through the "direct template synthesis" approach, which is a combination of classical template reactions of amines with acetone/formaldehyde and the "direct synthesis" method based on using elemental metals as starting materials. There is a significant decrease in the reaction time when the "direct synthesis" method is used compared to the conventional template condensation methods. X-ray crystallographic analyses of the complexes with the general formula M(L)ZnX4 and [(CuLZnCl3)-Zn-4](2) (M = Cu2+, Ni2+; L = L-1-L-3; X = Cl-, NCS-) reveal the presence of long intermolecular distance interactions, such as semi-coordination, S center dot center dot center dot S and H-bonding, in their crystal organization. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.031