[Zn(μ-PYPDMG)(N(SiMe3)2)]2 | 1000163-81-4

• 英文名称: [Zn(μ-PYPDMG)(N(SiMe3)2)]2
• CAS: 1000163-81-4
• 化学式: C₂₈H₆₈N₈Si₄Zn₂
• 分子量: 760.024
• InChiKey: KRQYRWGREMSREN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  哌啶 、 二甲基氢胺 、 zinc(II) chloride 、 lithium hexamethyldisilazane 在 n-BuLi 作用下， 以 乙醚 、 正己烷 为溶剂， 以12%的产率得到[Zn(μ-PYPDMG)(N(SiMe3)2)]2
  参考文献：
  名称：

  Synthesis and characterization of a series of zinc complexes stabilized by 1,1,3,3-tetraalkylguanidinate (TAG) ligands: [Zn(μ-TAG){N(SiMe3)2}]2

  摘要：

  A series of novel structurally varied low-coordinate zinc complexes utilizing 1,1,3,3-tetraalkylguanidinate (TAG) ligands were synthesized and characterized. Li(TAG) and lithium bis-trimethylsilylamide, LiN(SiMe3)(2), were successfully reacted with ZnCl2 in a 1:1 ratio to yield the corresponding dinuclear complexes with the general formula [Zn(mu-TAG) {N(SiMe3)(2)}](2), where[GRAPHICS]and[GRAPHICS]Compounds 1-6 were characterized by single-crystal X-ray diffraction. The bulk powders for all complexes were found to be in agreement with the crystal structures based on elemental analyses, FT-IR spectroscopy, and H-1 and C-13 NMR studies. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.08.013