diphenylmonochlorotin(IV) p-chlorobenzohydroxamate | 198630-99-8

• 英文名称: diphenylmonochlorotin(IV) p-chlorobenzohydroxamate
• CAS: 198630-99-8
• 化学式: C₁₉H₁₅Cl₂NO₂Sn
• 分子量: 478.95
• InChiKey: PSJLDWYFJQPQKQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  diphenylmonochlorotin(IV) p-chlorobenzohydroxamate 、 sodium salicylate 以 甲醇 为溶剂， 以59%的产率得到diphenyltin(IV) p-chlorobenzohydroxamate * salicylaldehyde
  参考文献：
  名称：

  Synthesis, Characterization and Thermal Studies of Di- and Triphenyltin(IV) Complexes ofp-Chloro- ANDp-Nitrobenzohydroxamic Acids

  摘要：

  Di- and triphenyltin(IV) complexes of the compositions Ph2SnCln(XBHA)(2-n) and Ph3Sn(XBHA) (where n=0 or 1, X=rho-Cl or rho-NO2 and BHA=anion of the hydroxamic acid, BH(2)A) have been synthesized by the reactions of Ph2SnCl2 or Ph3SnCl with the potassium salts of the respective rho-chloro or rho-nitrobenzo-hydroxamic acids in a MeOH/THF mixture. The complexes have been characterized by elemental analyses, molar conductance, molecular weight determinations and IR spectra. The results indicate that the ligand is bidentate, coordinating through the carbonyl and hydroxylamine oxygens. The reactions of Ph2SnCl(XBHA) with sodium derivatives of acetylacetone, dibenzoylmethane and salicylaldehyde (NaL) have led to the formation of mixed ligand complexes of the type Ph2Sn(XBHA) . L. Thermal decomposition of the complexes in an air stream yielded pure SnO2 at 700-800 degrees C.

  DOI：

  10.1080/00945719708000166
• 作为产物：
  描述：

  二苯基二氯化锡 、 potassium p-chlorobenzohydroxamate 以 四氢呋喃 、 甲醇 为溶剂， 以84%的产率得到diphenylmonochlorotin(IV) p-chlorobenzohydroxamate
  参考文献：
  名称：

  Synthesis, Characterization and Thermal Studies of Di- and Triphenyltin(IV) Complexes ofp-Chloro- ANDp-Nitrobenzohydroxamic Acids

  摘要：

  Di- and triphenyltin(IV) complexes of the compositions Ph2SnCln(XBHA)(2-n) and Ph3Sn(XBHA) (where n=0 or 1, X=rho-Cl or rho-NO2 and BHA=anion of the hydroxamic acid, BH(2)A) have been synthesized by the reactions of Ph2SnCl2 or Ph3SnCl with the potassium salts of the respective rho-chloro or rho-nitrobenzo-hydroxamic acids in a MeOH/THF mixture. The complexes have been characterized by elemental analyses, molar conductance, molecular weight determinations and IR spectra. The results indicate that the ligand is bidentate, coordinating through the carbonyl and hydroxylamine oxygens. The reactions of Ph2SnCl(XBHA) with sodium derivatives of acetylacetone, dibenzoylmethane and salicylaldehyde (NaL) have led to the formation of mixed ligand complexes of the type Ph2Sn(XBHA) . L. Thermal decomposition of the complexes in an air stream yielded pure SnO2 at 700-800 degrees C.

  DOI：

  10.1080/00945719708000166