| 351343-62-9

• CAS: 351343-62-9
• 化学式: C₃₇H₃₁FeN₂PPd
• 分子量: 696.907
• InChiKey: MTCFCCDKUNMZLM-XDTQWQDQSA-N

反应信息

• 作为产物：
  描述：

  potassium cyanide 、 在 AgNO₃ 作用下， 以 丙酮 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  Trans-influences in mononuclear cyclopalladated compounds containing a σ(Pd–Csp2, ferrocene) bond. X-ray crystal structures of [Pd{[(η5-C5H3)–CHN–CH2–C6H5]Fe(η5-C5H5)}(X)(PPh3)] with X−=Br− and I−

  摘要：

  The syntheses, characterization and study of the properties of cyclopalladated compounds of general formula: CPd{[(eta (5)-C5H3)CH=N-CH2-C6H5]Fe(eta (5)-C5H5)}(X)(PPh3)] with X- = Cl-, Br-, I-, CN-, SCN- or AcO- are reported. Compounds with X- = Br- and I- were characterized by X-ray diffraction, and their crystal structures revealed the existence of a weak C-H X interaction involving one of the -CH2- type hydrogen atoms bound to the imine nitrogen. Comparison of the spectroscopic properties of these compounds has allowed us to elucidate the influence of the monoanionic ligand, X-, on a tuans-arrangement to the metallated carbon atom upon the environment of the iron(II). Theoretical studies based on the semiempirical PM3(tm) were also been carried out to clarify the effects produced by the X- ligand on the ring current of the metallated C,H, ring of the ferrocenyl fragment. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00900-1