[In((SeP(i-Pr)2)N)(S2CNEt2)2] | 882571-74-6

• 英文名称: [In((SeP(i-Pr)2)N)(S2CNEt2)2]
• CAS: 882571-74-6
• 化学式: C₂₂H₄₈InN₃P₂S₄Se₂
• 分子量: 817.595
• InChiKey: QMCPVIAFFUUQRY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二硫化碳 、 、 二乙胺 在 NaOH 作用下， 以 四氢呋喃 为溶剂， 以72%的产率得到[In((SeP(i-Pr)2)N)(S2CNEt2)2]
  参考文献：
  名称：

  Synthesis of novel mixed indium(III) chalcogenolato complexes: Potential precursors for indium chalcogenides

  摘要：

  Novel organometallic and metal-organic indium complexes, [Et2In(OS2CNMe '' Bu)](2) (1), [In{SeP ' Pr-2)(2)N}(S2CNEt2)(2)] (2) and [In{(SeP ' Pr-2)(2)N}(S2P ' BU2)(2)] (3), have been synthesised and characterised. Compound (1) was formed by the insertion of oxygen atoms into the M-S bonds of thiocarbamate ligands, whereas the mixed-chalcogenide complexes (2) and (3) were prepared by the reaction of Na(S2CNEt2)(2) or Na(S2P ' Bu-2)(2) with In[(SeP ' Pr-2)(2)N](2)Cl. The structures of all three compounds were determined by X-ray single crystallographic methods. The dimeric structure of (1) consists of two five membered and one four membered rings formed by chelating and bridging of both dithioperoxycarbarnato ligands. The structures of both (2) and (3) are based on monomers in each case the coordination around indium is distorted octahedral. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.09.012