[RuH(C2C2H)(CO)2(triphenylphosphine)2] | 871128-13-1

• 英文名称: [RuH(C2C2H)(CO)2(triphenylphosphine)2]
• CAS: 871128-13-1
• 化学式: C₄₂H₃₂O₂P₂Ru
• 分子量: 731.732
• InChiKey: SUDDEKOLZBNAMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [RuH(C2C2H)(CO)2(triphenylphosphine)2] 、 二苯基乙炔 以 not given 为溶剂， 生成 [Ru(.eta2-PhC2Ph)(CO)2(triphenylphosphine)2]
  参考文献：
  名称：

  A Bimetallic Complex Spanned by the C₄H Ligand:  Synthesis of [Cl(CO)₂L₂RuC⋮CCHCRuL₂(η-C₅H₅)]PF₆ (L = PPh₃)

  摘要：

  The synthesis of the first example of a bimetallic complex spanned by the C4H alkynylvinylidene ligand, [Cl(CO)(2)L2RuC equivalent to CCH=C=RuL2(eta-C5H5)]PF6 (L = PPh3), is reported: the reaction of [Ru(CO)(2)L-3] with butadiyne provides [RuH(C equivalent to CC equivalent to CH)(CO)(2)L-2], which is converted to the chloro derivative [RuCl(C equivalent to CC equivalent to CH)(CO)(2)L-2] by N-chlorosuccinimide. Subsequent treatment with [Ru(tht)L-2(eta-C5H5)]PF6 provides [Cl(CO)(2)L2RuC equivalent to CCH equivalent to C equivalent to RuL2(eta-C5H5)]PF6, deprotonation of which affords [Cl(CO)(2)L2RuC equivalent to CC equivalent to CRuL2(eta-C5H5)].

  DOI：

  10.1021/om050800o
• 作为产物：
  描述：

  {ruthenium(0) dicarbonyltris(triphenylphosphine)} 、 1,4-双(三甲硅基)-1,3-丁二炔 、 水 在 (C₄H₉)4NF 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 以85%的产率得到[RuH(C2C2H)(CO)2(triphenylphosphine)2]
  参考文献：
  名称：

  A Bimetallic Complex Spanned by the C₄H Ligand:  Synthesis of [Cl(CO)₂L₂RuC⋮CCHCRuL₂(η-C₅H₅)]PF₆ (L = PPh₃)

  摘要：

  The synthesis of the first example of a bimetallic complex spanned by the C4H alkynylvinylidene ligand, [Cl(CO)(2)L2RuC equivalent to CCH=C=RuL2(eta-C5H5)]PF6 (L = PPh3), is reported: the reaction of [Ru(CO)(2)L-3] with butadiyne provides [RuH(C equivalent to CC equivalent to CH)(CO)(2)L-2], which is converted to the chloro derivative [RuCl(C equivalent to CC equivalent to CH)(CO)(2)L-2] by N-chlorosuccinimide. Subsequent treatment with [Ru(tht)L-2(eta-C5H5)]PF6 provides [Cl(CO)(2)L2RuC equivalent to CCH equivalent to C equivalent to RuL2(eta-C5H5)]PF6, deprotonation of which affords [Cl(CO)(2)L2RuC equivalent to CC equivalent to CRuL2(eta-C5H5)].

  DOI：

  10.1021/om050800o