trans-[rhodium(II)(CO)Cl(P(C6H4O)3)2(C14H28)3] | 908127-28-6

• 英文名称: trans-[rhodium(II)(CO)Cl(P(C6H4O)3)2(C14H28)3]
• CAS: 908127-28-6
• 化学式: C₇₉H₁₀₈ClO₇P₂Rh
• 分子量: 1370.03
• InChiKey: ZYGUIHHTQZEPRM-IPNCCLMQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三甲基膦 、 trans-[rhodium(II)(CO)Cl(P(C6H4O)3)2(C14H28)3] 以 正己烷 、 甲苯 为溶剂， 以83 %的产率得到6,21,31,46,55,70-Hexaoxa-1,26-diphosphaoctacyclo[24.24.24.22,5.222,25.227,30.247,50.251,54.271,74]hexaoctaconta-2(86),3,5(85),22,24,27(82),28,30(81),47(80),48,50(79),51,53,71,73,75,77,83-octadecaene
  参考文献：
  名称：

  Square-Planar and Octahedral Gyroscope-Like Metal Complexes Consisting of Dipolar Rotators Encased in Dibridgehead Di(triaryl)phosphine Stators: Syntheses, Structures, Dynamic Properties, and Reactivity

  摘要：

  For a variety of purposes, it is of interest to embed metals in cagelike trans-spanning di(triaryl)phosphine ligands. Toward this end, a combination of P(p-C6H4O(CH2)mCH═CH2)3 [3; m = 4 (a), 5 (b), 6 (c), and 7 (d)], [Rh(COD)(μ-Cl)]2, and CO gives square-planar trans-Rh(CO)(Cl)[P(p-C6H4O(CH2)mCH═CH2)3]2 (4a–4d). Reactions of 4b–4d with Grubbs’ catalyst (first generation) and then H2 (catalyst PtO2)

  DOI：

  10.1021/acs.inorgchem.2c02855
• 作为产物：
  描述：

  trans-[rhodium(II)(CO)Cl(P(C6H4O)3)2(C6H12CHCHC6H12)3] 在 platinum(IV) oxide 、 氢气 作用下， 以 四氢呋喃 为溶剂， 以53 %的产率得到trans-[rhodium(II)(CO)Cl(P(C6H4O)3)2(C14H28)3]
  参考文献：
  名称：

  Square-Planar and Octahedral Gyroscope-Like Metal Complexes Consisting of Dipolar Rotators Encased in Dibridgehead Di(triaryl)phosphine Stators: Syntheses, Structures, Dynamic Properties, and Reactivity

  摘要：

  For a variety of purposes, it is of interest to embed metals in cagelike trans-spanning di(triaryl)phosphine ligands. Toward this end, a combination of P(p-C6H4O(CH2)mCH═CH2)3 [3; m = 4 (a), 5 (b), 6 (c), and 7 (d)], [Rh(COD)(μ-Cl)]2, and CO gives square-planar trans-Rh(CO)(Cl)[P(p-C6H4O(CH2)mCH═CH2)3]2 (4a–4d). Reactions of 4b–4d with Grubbs’ catalyst (first generation) and then H2 (catalyst PtO2)

  DOI：

  10.1021/acs.inorgchem.2c02855

文献信息

• “Giant” Gyroscope-Like Molecules Consisting of Dipolar Cl-Rh-CO Rotators Encased in Three-Spoke Stators That Define 25–27-Membered Macrocycles
  作者：Leyong Wang、Frank Hampel、John A. Gladysz

  DOI：10.1002/anie.200601191

  日期：2006.6.26