2-formyl-5-ruthenocenylthiophene | 1007403-61-3

• 英文名称: 2-formyl-5-ruthenocenylthiophene
• CAS: 1007403-61-3
• 化学式: C₁₅H₁₂ORuS
• 分子量: 341.396
• InChiKey: QPKBLZHPYURJQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-formyl-5-ruthenocenylthiophene 、 ruthenoceny(triphenyl)phosphonium bromide 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 生成 5-(2'-ruthenocenyl-E-ethenyl)-2-ruthenocenylthiophene
  参考文献：
  名称：

  Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives

  摘要：

  Binuclear ruthenocenes bridged by ethenes and thiophene derivatives, Rc-CH=CH-Z-Rc and Rc*-CH=CH-Z CH=CH-Rc* (Z = thiophene, thieno[3,2-b]thiophene, and 2,2'-bithiophene; Rc = ruthenocenyl, R* = 1',2',3',4',5'-pentamethylruthenocenyl) were prepared. These complexes showed a one-step two-electron redox wave in the cyclic voltammograms, in contrast to the benzenoid-bridged dinuclear ruthenocenes. The chemical oxidation of the Rc-CH=CH-Z-Rc complexes gave no stable oxidized species. The two-electron oxidized species of the Rc*-CH=CH-Z-CH=CH-Rc* complexes were comparably stable and contained a fulvene-complex type structure. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.057
• 作为产物：
  描述：

  2-ruthenocenylthiophene 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 以 1,2-二氯乙烷 、 N,N-二甲基甲酰胺 为溶剂， 以84%的产率得到2-formyl-5-ruthenocenylthiophene
  参考文献：
  名称：

  Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives

  摘要：

  Binuclear ruthenocenes bridged by ethenes and thiophene derivatives, Rc-CH=CH-Z-Rc and Rc*-CH=CH-Z CH=CH-Rc* (Z = thiophene, thieno[3,2-b]thiophene, and 2,2'-bithiophene; Rc = ruthenocenyl, R* = 1',2',3',4',5'-pentamethylruthenocenyl) were prepared. These complexes showed a one-step two-electron redox wave in the cyclic voltammograms, in contrast to the benzenoid-bridged dinuclear ruthenocenes. The chemical oxidation of the Rc-CH=CH-Z-Rc complexes gave no stable oxidized species. The two-electron oxidized species of the Rc*-CH=CH-Z-CH=CH-Rc* complexes were comparably stable and contained a fulvene-complex type structure. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.057