((Co2(CO)6(μ-HCC-))-CH2NH)2C=O | 377778-55-7

• 英文名称: ((Co2(CO)6(μ-HCC-))-CH2NH)2C=O
• CAS: 377778-55-7
• 化学式: C₁₉H₈Co₄N₂O₁₃
• 分子量: 708.251
• InChiKey: FJPLNUXATWJNST-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 炔丙胺 以 四氢呋喃 为溶剂， 以54%的产率得到((Co2(CO)6(μ-HCC-))-CH2NH)2C=O
  参考文献：
  名称：

  通过基于尿素的配体连接两个炔桥双齿二配体配合物：[[[Co（2）（CO）（6）（mu-HC与C-）]-CH（2）NH]的合成，光谱和结构表征（2）C ＝ O。

  摘要：

  Treatment of Co-2(CO)(8) with HC equivalent to CCH2NH2 under mild reaction conditions yielded an unusual complex of {[Co-2(CO)(6)(mu -HC equivalent toC-)]-CH2NH}(2)C=O, 1. The structure of 1 was established by X-ray diffraction analysis. The compound 1 can be viewed as two propargylamine-bridged dicobalt complexes coupled by a carbonyl group. Obviously, carbonylation of a primary amine took place during this reaction.

  DOI：

  10.1021/ic010071e