[cis,trans-bis(diphenylmethylphosphine)(carbonyl)(allylimido)tungsten(II) dichloride] | 156843-84-4

• 英文名称: [cis,trans-bis(diphenylmethylphosphine)(carbonyl)(allylimido)tungsten(II) dichloride]
• CAS: 156843-84-4
• 化学式: C₃₀H₃₁Cl₂NOP₂W
• 分子量: 738.286
• InChiKey: HOHGHIPXPGSCOU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [cis,trans-bis(diphenylmethylphosphine)(carbonyl)(allylimido)tungsten(II) dichloride] 、 四乙基氯化铵 在 t-BuLi 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and molecular structure of the organometallic allylimido complex [cis,trans-WCl2(Ph2PMe)2(CO)(NCH2CHC2)]

  摘要：

  Addition of allyl isocyanate to [WCl2(Ph2PMe)4] results in oxidative addition of the nitrogen-carbon bond to the metal centre to afford the allylimido complex [cis,trans-WCl2(Ph2PMe)2(CO)(NCH2CH=CH2)], which has been crystallographically characterized. Reaction with t-butyllithium results in rapid deprotonation of one of the alpha-hydrogens of the allyl moiety, a process which is reversed upon addition of water.

  DOI：

  10.1016/0022-328x(94)88120-0
• 作为产物：
  描述：

  W^IICl2(PMePh2)4 、 3-异氰酸丙烯 以 甲苯 为溶剂， 以85%的产率得到[cis,trans-bis(diphenylmethylphosphine)(carbonyl)(allylimido)tungsten(II) dichloride]
  参考文献：
  名称：

  Synthesis and molecular structure of the organometallic allylimido complex [cis,trans-WCl2(Ph2PMe)2(CO)(NCH2CHC2)]

  摘要：

  Addition of allyl isocyanate to [WCl2(Ph2PMe)4] results in oxidative addition of the nitrogen-carbon bond to the metal centre to afford the allylimido complex [cis,trans-WCl2(Ph2PMe)2(CO)(NCH2CH=CH2)], which has been crystallographically characterized. Reaction with t-butyllithium results in rapid deprotonation of one of the alpha-hydrogens of the allyl moiety, a process which is reversed upon addition of water.

  DOI：

  10.1016/0022-328x(94)88120-0