iodocyclopentadienyl(triethylphosphine)carbonyliron(II) | 33154-70-0

• 英文名称: iodocyclopentadienyl(triethylphosphine)carbonyliron(II)
• CAS: 33154-70-0
• 化学式: C₁₂H₂₀FeIOP
• 分子量: 394.015
• InChiKey: QSAFITBHWAPREP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (3,6-dimethylthieno[3,2-b]thiophene-2,5-diyl)bis(trimethylstannane) 、 iodocyclopentadienyl(triethylphosphine)carbonyliron(II) 在 双(乙腈)氯化钯(II) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以24%的产率得到(P(C₂H₅)3)(CO)(C₅H₅)FeC(O)((CH₃SC₃)4)Sn(CH₃)3
  参考文献：
  名称：

  Synthesis of iron thienyl complexes

  摘要：

  Dimetallation of thiophene (TH2), bithiophene (BTH2) and 3,6-dimethyl[3,2-b]thienothiophene (TTH2) using a slight excess of butyl lithium, followed by the addition of [FeCp(CO)(2)I], resulted in the formation of [2,5-{FeCP(CO)(2)}(2)T], 1 and [2-{FeCp (CO)(2)} T]. The analogous reaction with bithiophene as precursor afforded similar products [2,2'-{FeCp(CO)(2)}(2)BT] 2 and [2-{FeCp (CO)(2)} BTH] 3. In addition to the expected mono- ([2-{FeCP(CO)(2)}-TTH] 4) and binuclear ([2,2'-{FeCP(CO)(2)}(2)-TT] 5) products, dimetallation of 3,6-dimethyl[3,2-b]thienothiophene and the subsequent reaction with [FeCp(CO)21] yielded carbonyl inserted mono-([2-{FeCP(CO)(2)}C(O)-{TT}(2)H] 6) and binuclear ([2-{FeCP(CO)(2)}C(O)-{TT}(2)-2'-{FeCp(CO)(2)}] 7) carbon-carbon coupled products. The precursor [2,7-{SnMe3}(2)-TT] (8) was prepared and reacted with [FeCp(CO)(PEt3)I] in the presence of a palladium catalyst to afford [2- FeCp(CO)(PEt3) C(O)-{TT}(2)-2'-{SnMe3}] 10. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.03.022
• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 、 三乙基膦 以 四氢呋喃 为溶剂， 生成 iodocyclopentadienyl(triethylphosphine)carbonyliron(II)
  参考文献：
  名称：

  Mixed phosphine/carbonyl derivatives of heterobimetallic copper–iron and copper–tungsten catalysts

  摘要：

  Evolution of dihydrogen was observed from reactions of protic metal-hydride complexes FeCp(CO)(PR3) H and WCp*(CO)(2)(PR3)H with hydridic (NHC)CuH complexes, providing access to several heterobimetallic (NHC)Cu-FeCp(CO)(PR3) and (NHC)Cu-WCp*(CO)(2)(PR3) complexes that are the mixed phosphine/ carbonyl derivatives of previously studied catalysts for C-H borylation (NHC = N-heterocyclic carbene). The new complexes were characterized by multinuclear NMR spectroscopy, FT-IR spectroscopy, and in some cases X-ray crystallography. In one case, a (NHC)Cu(mu(2) -H)(2)FeCp(PPh3) complex was structurally characterized as the decomposition product of an unstable (NHC)Cu-FeCp(CO)(PPh3) derivative. Preliminary trials in C-H borylation catalysis are reported, including measurable activity under photochemical conditions. (C) 2018 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2018.09.062

文献信息

• Scharrer, Eric; Chang, Seok; Brookhart, Maurice, Organometallics, 1995, vol. 14, # 12, p. 5686 - 5694
  作者：Scharrer, Eric、Chang, Seok、Brookhart, Maurice

  DOI：——

  日期：——