bis(diethyldithiocarbamato)dioxomolybdenum(IV)[(Et2NCS2)2MoO2] or α,β,γ,δ-tetraphenylporphinato-oxochromium(IV)[(TPP)CrO] and FeII, MnII, or MoIV complexes bearing pentadentate salicylideneamine or dithiocarbamate ligands lead to the formation of heterobinuclear µ-oxo bridged complexes; some degree of magnetic coupling is observed between each combination of metals.
双(
二乙基二
硫代
氨基甲酸酯)二氧
钼钼(IV)[(Et 2
NCS 2)2 MoO 2 ]或α,β,γ,δ-
四苯基卟啉-氧
铬(IV)[(
TPP)CrO]与Fe II,Mn II,带有五齿
水杨基
亚胺或二
硫代
氨基甲酸酯
配体的Mo IV配合物导致形成异双核µ-氧代桥联配合物;或 在每种
金属组合之间观察到一定程度的磁耦合。