1,4,7,10,13,25,28,31,34-nonathia[10.13]ferrocenophane | 93347-30-9

• 英文名称: 1,4,7,10,13,25,28,31,34-nonathia[10.13]ferrocenophane
• CAS: 93347-30-9
• 化学式: C₃₄H₄₄Fe₂S₉
• 分子量: 853.011
• InChiKey: OGHBDYSKYCNMCS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,1'-bis(2-chloroethylthio)ferrocene 、 1,2-乙二硫醇 在 sodium hydroxide 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 以50.5%的产率得到1,4,7,10-tetrathia{10}ferrocenophane
  参考文献：
  名称：

  Syntheses of Polythia[n]ferrocenophanes and Polythia[n.n]ferrocenophanes. Marocyclic Polysulfide Ligands Containing a Ferrocene Nucleus

  摘要：

  1,1′-Bis(2-chloroethylthio)ferrocene reacted with disodium 1,2-ethanedithiolate to give 1,4,7,10-tetrathia[10]ferrocenophane and 1,4,7,10,22,25,28,31-octathia[10.10]ferrocenophane, along with unexpected 1,4,7-trithia[7]ferrocenophane, 1,4,7,10,13-pentathia[13]ferrocenophane and 1,4,7,10,13,25,28,31,34-nonathia[10.13]ferrocenophane. The reaction of 1,1′-bis(2-chloroethylthio)ferrocene with disodium 1,3-propanedithiolate gave 1,4,-8,11-tetrathia[11]ferrocneophane. 1,1′-Bis(3-chloropropylthio)ferrocene reacted with disodium 1,2-ethanedithiolate and 1,3-propanedithiolate to afford 1,5,8,12-tetrathia[12]ferrocenophane and 1,5,8,12,24,27,31,34-octathia[12.12]ferrocenophane, and 1,5,9,13-tetrathia[13]ferrocenophane, respectively. The structural features of the above polythia[n]ferrocenophanes are also discussed on the bases of their spectral data.

  DOI：

  10.1246/bcsj.57.1929