[1-n-butyl-3-methylimidazolium]NbCl6 | 370569-84-9

• 英文名称: [1-n-butyl-3-methylimidazolium]NbCl6
• CAS: 370569-84-9
• 化学式: C₈H₁₅N₂*Cl₆Nb
• 分子量: 444.845
• InChiKey: QHFOKZZBKBDTQM-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  五氯化铌 、 氯化(1-丁基-3-甲基咪唑) 生成 [1-n-butyl-3-methylimidazolium]NbCl6
  参考文献：
  名称：

  An efficient organic solvent-free solution-processing strategy for high-mobility metal chalcogenide film growth

  摘要：

  通过化学溶液法生长高质量金属硫属化物薄膜的主要挑战之一是在制造过程中避免使用挥发性/有害的有机溶剂。

  DOI：

  10.1039/c6gc02489k

文献信息

• The use of Differential Scanning Calorimetry (DSC) to characterize phase diagrams of ionic mixtures of 1-n-butyl-3-methylimidazolium chloride and niobium chloride or zinc chloride
  作者：Melquizedeque B. Alves、Alexandre P. Umpierre、Vianney O. Santos Jr.、Valerio C.D. Soares、Jairton Dupont、Joel C. Rubim、Paulo A.Z. Suarez

  DOI：10.1016/j.tca.2010.01.023

  日期：2010.4

  The thermal behavior of the BMICl/NbCl5 and BMICl/ZnCl2 mixtures was investigated by DSC and correlated with previous studies using Raman spectroscopy. Combining both results, it was possible to built the phase diagram for these mixtures and suggest the formation of different compounds and the equilibria in the euthetic mixtures. The phase diagram of BMICl and NbCl5 mixture showed that probably only one compound is formed at X-NbCl5 = 0.50 (BMINbCl6) and euthetic mixtures are present in the 0 <= X-NbCl5 <= 0.50 composition range. For the BMICl and ZnCl2, four different compounds were detected: (BMI)(2)(ZnCl4) for X-ZnCl2 =0.35; (BMI)(2)(Zn2Cl6); (BMI)(2)(Zn3Cl8) and (BMI)(2)(Zn4Cl10) for X-ZnCl2 =0.70, and between these isoplets euthetic mixtures are formed. (C) 2010 Elsevier B.V. All rights reserved.