cis-(3-chloropyridine)(piperidine)tetracarbonylmolybdenum(0) | 142771-24-2

• 英文名称: cis-(3-chloropyridine)(piperidine)tetracarbonylmolybdenum(0)
• CAS: 142771-24-2
• 化学式: C₁₄H₁₅ClMoN₂O₄
• 分子量: 406.677
• InChiKey: IKFLBZWOUYWEEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-氯吡啶 、 cis-tetracarbonylbis(piperidine)molybdenum 以 N,N-二甲基甲酰胺 为溶剂， 生成 cis-(3-chloropyridine)(piperidine)tetracarbonylmolybdenum(0)
  参考文献：
  名称：

  Ligand effects in the substitution chemistry of cis-bis(piperidine)tetracarbonylmolybdenum(O). A molybdenum-95 NMR study

  摘要：

  Molybdenum-95 NMR chemical shifts are reported for a series of Mo(O) compounds of the type Mo(CO)4(pip)(2-n)L(n) (n = 1, 2; L = substituted pyridine ligands). The delta(Mo-95) values correlate well with the pK(a) values for the substituted pyridines; for the n = 1 series, delta(Mo-95) ranges from - 1053 ppm (pK(a) = 1.86 for (CN) to - 1120 ppm (pK(a) = 9.61 for 4-NMe2). The effects of solvent polarity and some in situ reactivity studies are described and the nature of the Mo-L bond compared to that with piperidine and some other ligands is discussed.

  DOI：

  10.1016/0584-8539(92)80084-a