| 1446514-20-0

• CAS: 1446514-20-0
• 化学式: C₃₂H₂₁ClN₃O₄Re
• 分子量: 733.196
• InChiKey: YGZKSLHLNAKOKV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 水 作用下， 以 乙腈 为溶剂， 反应 18.0h， 以96%的产率得到
  参考文献：
  名称：

  ON-OFF Luminescence Signaling of Hybrid Organic–Inorganic Switches

  摘要：

  The dyads 1(OFF) and 2(OFF) were prepared by combining the inorganic luminophores [Ru(phen)(2)(2-[imidazol-2-yl]pyridine)](2+) and (Re(CO)(3)Cl(2-[imidazol-2-yl]pyridine)] with 2-(anthracen-9-yl)-4-methylphenol as a second photoactive moiety. In both cases, the inorganic unit operates as the emitter, whereas the organic part acts as a controller. Emission of the inorganic luminophore can be reversibly switched ON and OFF by adjusting the energetic level of the (3)pi-pi* state of the appended anthracene unit through either dearomatization using a photohydration or aromatization applying a thermal dehydration. Emission of both switches is reversibly recorded and erased multiple times without significant degradation.

  DOI：

  10.1021/ic400676j
• 作为产物：
  描述：

  9-溴蒽 在 四(三苯基膦)钯 、 正丁基锂 、 三溴化硼 、 potassium carbonate 作用下， 以 四氢呋喃 、 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 83.5h， 生成
  参考文献：
  名称：

  ON-OFF Luminescence Signaling of Hybrid Organic–Inorganic Switches

  摘要：

  The dyads 1(OFF) and 2(OFF) were prepared by combining the inorganic luminophores [Ru(phen)(2)(2-[imidazol-2-yl]pyridine)](2+) and (Re(CO)(3)Cl(2-[imidazol-2-yl]pyridine)] with 2-(anthracen-9-yl)-4-methylphenol as a second photoactive moiety. In both cases, the inorganic unit operates as the emitter, whereas the organic part acts as a controller. Emission of the inorganic luminophore can be reversibly switched ON and OFF by adjusting the energetic level of the (3)pi-pi* state of the appended anthracene unit through either dearomatization using a photohydration or aromatization applying a thermal dehydration. Emission of both switches is reversibly recorded and erased multiple times without significant degradation.

  DOI：

  10.1021/ic400676j