[(thf)(dme)Ca(C6H3-2,6-tol2)HBEt3] | 1261287-12-0

• 英文名称: [(thf)(dme)Ca(C6H3-2,6-tol2)HBEt3]
• 英文别名: [(THF)(DME)Ca(2,6-(tol)2C6H3)(HBEt3)]
• CAS: 1261287-12-0
• 化学式: C₃₄H₅₁BCaO₃
• 分子量: 558.666
• InChiKey: VGXYGVLOZSNXRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙二醇二甲醚 、 [2,6-(tol)2C6H3-Ca(thf)3I] 、 三乙基氢硼化钾 以 四氢呋喃 、 甲苯 为溶剂， 反应 12.0h， 以70%的产率得到[(thf)(dme)Ca(C6H3-2,6-tol2)HBEt3]
  参考文献：
  名称：

  Synthesis and characterization of rare examples of stable potassium and arylcalcium triethylboranate complexes

  摘要：

  Stabilization of potassium triethylboranate can be achieved in solution as well as in the solid state with tridentate 1,3,5-trimethyl-1,3,5-triazinane (tmta) as dimeric [(tmta)K(mu-H)BEt3](2) (1). The metathesis reaction of the post- Grignard reagent [2,6-(tol)(2)C6H3-Ca(thf)(3)I] (2) with potassium triethylboranate yields an unusual hydrogen bridged organocalcium contact ion pair as hydrocarbon soluble [(thf)(dme)Ca(C6H3-2,6-tol(2))HBEt3] (3) which shows no tendency to dismutate to the homoleptic derivatives. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.08.018