2,6-diethyl-4,4-diphenyl-1,3,5,7-tetramethyl-8-(4-methylphenyl)-4-bora-3a,4a-diaza-s-indacene | 1256972-44-7

• 英文名称: 2,6-diethyl-4,4-diphenyl-1,3,5,7-tetramethyl-8-(4-methylphenyl)-4-bora-3a,4a-diaza-s-indacene
• CAS: 1256972-44-7
• 化学式: C₃₆H₃₉BN₂
• 分子量: 510.53
• InChiKey: QBUHLUJMUGENRP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-(4-methylphenyl)-4-bora-3a,4a-diaza-s-indacene 、 苯基锂 以 四氢呋喃 、 乙醚 、 环己烷 为溶剂， 反应 48.0h， 以48%的产率得到2,6-diethyl-4,4-diphenyl-1,3,5,7-tetramethyl-8-(4-methylphenyl)-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  Strategy for the increasing the solid-state fluorescence intensity of pyrromethene–BF2 complexes

  摘要：

  In this study, we attempted to increase the fluorescence quantum yield of pyrromethene-BF2 complex (BODIPY) in the solid state by introducing bulky groups as substituents at the boron atom. Although the BF2 complex did not exhibit any fluorescence in the solid state (Phi(f) = 0.00), the B(OMe)(2), B(OPh)(2), and BPh2 complexes did show solid-state fluorescence with quantum yields of 0.02, 0.04, and 0.22, respectively. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.106