(N[2-P(i)Pr2-4-methylphenyl]2)Ti=NSiMe3(CH2(t)Bu) | 1312365-51-7

• 英文名称: (N[2-P(i)Pr2-4-methylphenyl]2)Ti=NSiMe3(CH2(t)Bu)
• CAS: 1312365-51-7
• 化学式: C₃₄H₆₀N₂P₂SiTi
• 分子量: 634.777
• InChiKey: RDLTUROZOHLQPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  叠氮基三甲基硅烷 、 [(N[2-PiPr2-4-methylphenyl]2)Ti(η2-H2C=CH2)(CH2tBu)] 以 not given 为溶剂， 以99%的产率得到(N[2-P(i)Pr2-4-methylphenyl]2)Ti=NSiMe3(CH2(t)Bu)
  参考文献：
  名称：

  Room Temperature Dehydrogenation of Ethane to Ethylene

  摘要：

  The transient titanium alkylidyne, (PNP)Ti (CBu)-Bu-t (PNP = N[2-(PPr2)-Pr-i-4-methylphenyl](2)(-)), activates a C-H bond of ethane at room temperature, and a beta-hydrogen of the resulting ethyl ligand is subsequently transferred to the adjacent alkylidene ligand to form an ethylene adduct of titanium. Treatment of the ethylene complex with two-electron oxidants such as organic azides results in extrusion of ethene concomitant with formation of a mononuclear titanium imido complex.

  DOI：

  10.1021/ja202316m