| 944069-66-3

• CAS: 944069-66-3
• 化学式: C₂₄BF₂₀*C₂₆H₂₉B₂P₂
• 分子量: 1104.13
• InChiKey: ZQUHQCYWSPSUHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,2-bis(diphenylphosphino)ethane bis(borane) 、 三苯碳四(五氟苯基)硼酸盐 以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Electrophilic Activation of Lewis Base Complexes of Borane with Trityl Tetrakis(pentafluorophenyl)borate

  摘要：

  Borenium ions do not accumulate under the conditions of hydride abstraction from Lewis base borane complexes (L center dot BH3) using trityl cation because subsequent rapid reaction with L center dot BH3 occurs to form B-H-B bonds. The hydride-bridged cations are sufficiently stabilized to resist abstraction of the remaining hydride by excess trityl cation; however, reversible cleavage of the 3c2e bond does take place to release borenium ion equivalents, as evidenced by interaction with weak nucleophiles.

  DOI：

  10.1021/om070228w