[Copper(II)(3,3-bis(2'-aminoethylaminomethyl)oxetane)Cl]PF6 | 896101-15-8

• 英文名称: [Copper(II)(3,3-bis(2'-aminoethylaminomethyl)oxetane)Cl]PF6
• CAS: 896101-15-8
• 化学式: C₉H₂₂ClCuN₄O*F₆P
• 分子量: 446.263
• InChiKey: XCHSSTRDRVYLST-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3,3-双(氯甲基)氧杂环丁烷 、 sodium hexaflorophosphate 、 copper(II) choride dihydrate 、 sodium perchlorate 、 乙二胺 在 NaOH 作用下， 以 乙二胺 为溶剂， 生成 [Copper(II)(3,3-bis(2'-aminoethylaminomethyl)oxetane)Cl]PF6 、
  参考文献：
  名称：

  Polyamines from polyols – Pathways to azamacrocycles with hydroxymethyl pendent groups

  摘要：

  Several pathways to macromonocylic polyamine ligands with pendent hydroxymethyl substituents have been explored. The new ligands have all been characterised by single-crystal, X-ray structure determinations on their complexes with Co(III) (one case) and Cu(II). As in some related systems, four-membered ring species, here oxetanes rather than azetidines, appear to be involved as reaction intermediates and can be quite readily isolated, providing reactants of potential for the construction of even more complicated multidentate ligands. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.11.024