(η5-1-C(OH)(Me)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese | 1012785-86-2

• 英文名称: (η5-1-C(OH)(Me)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese
• CAS: 1012785-86-2；1013331-87-7
• 化学式: C₂₂H₁₉MnO₅S
• 分子量: 450.394
• InChiKey: FHEYRKWXZUSZEC-YJEIKEMPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-1-C(OH)(Me)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese 在 HBF₄*OMe₂ 作用下， 以 二氯甲烷 为溶剂， 以71%的产率得到(η5-1-C(CH2)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese
  参考文献：
  名称：

  Synthesis and Structure of (η⁵-cyclohexadienyl)Mn(CO)₃ and Cationic (η⁶-arene)Mn(CO)₃ Complexes Comprising a Double Bond Conjugated to the π System

  摘要：

  Addition of a Grignard reagent to keto-substituted (eta(5)-cyclohexadienyl)Mn(CO)(3) complexes leads to the corresponding alcohols in very good yields. After acidic treatment, dehydration occurs, which gives rise to the formation of unprecedented (eta(5)-cyclohexadienyl)Mn(CO)(3) complexes substituted by a double bond conjugated to the pi system as the major compounds, along with uncoordinated trienones due to the rearrangement of the intermediate carbocation. The structure of one of these eta(5) complexes has been determined by X-ray crystallography as well as one of the corresponding cationic (eta(6)-arene)Mn(CO)(3) complexes formed upon hydride abstraction.

  DOI：

  10.1021/om7010672
• 作为产物：
  描述：

  (η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese 、 水 、 甲基氯化镁 以 四氢呋喃 为溶剂， 以86%的产率得到(η5-1-C(OH)(Me)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese
  参考文献：
  名称：

  Synthesis and Structure of (η⁵-cyclohexadienyl)Mn(CO)₃ and Cationic (η⁶-arene)Mn(CO)₃ Complexes Comprising a Double Bond Conjugated to the π System

  摘要：

  Addition of a Grignard reagent to keto-substituted (eta(5)-cyclohexadienyl)Mn(CO)(3) complexes leads to the corresponding alcohols in very good yields. After acidic treatment, dehydration occurs, which gives rise to the formation of unprecedented (eta(5)-cyclohexadienyl)Mn(CO)(3) complexes substituted by a double bond conjugated to the pi system as the major compounds, along with uncoordinated trienones due to the rearrangement of the intermediate carbocation. The structure of one of these eta(5) complexes has been determined by X-ray crystallography as well as one of the corresponding cationic (eta(6)-arene)Mn(CO)(3) complexes formed upon hydride abstraction.

  DOI：

  10.1021/om7010672