| 88510-23-0

• CAS: 88510-23-0
• 化学式: C₁₆H₂₀S₄Ti
• 分子量: 388.479
• InChiKey: ATSGQSGFXOYOHU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dichloroheptasulfane 、 以 二硫化碳 为溶剂， 生成 二氯二茂钛
  参考文献：
  名称：

  Preparation of spiro-cyclic organic polysulfanes of type C6H10Sn and x-ray structural analysis of C6H10S11, a derivative of cyclo-dodecasulfur

  摘要：

  AbstractBy reaction of (C5H5)2Ti(μ‐S2)2C6H10 3 with S2Cl2 7,8,9,10,11,12‐hexathiaspiro‐[5.6]dodecane 4 is prepared (yield 51%) and characterized by UV, IR, Raman, mass, and NMR spectra (1H, 13C). The seven‐membered CS6 ring undergoes pseudorotation in solution. With S7Cl2 the complex 3 yields 7,8,9,10,11,12,13,14,15,16,17‐undecathiaspiro[5.11]heptadecane 5 (yield 23%). The yellow, monoclinic crystals of 5 consist of spirocyclic C6H10S11 molecules with the C6 ring in a chair‐conformation while the CS11 ring is of the same conformation as cyclododecasulfur S12. UV, IR, Raman, mass and NMR‐spectra of 5 are reported. A mixture of dichlorosulfanes SnCl2 (n = 1 ‐8) reacts with 3 to give the homologous series C6H10Sm which was characterized by reversed‐phase HPLC for m = 5 – 14.

  DOI：

  10.1002/zaac.19966220924
• 作为产物：
  描述：

  bis(η-cyclopentadienyl)titana(IV)cyclohexasulfane 、 环己酮 在 (NH₄)2S 作用下， 以 further solvent(s) 为溶剂， 生成
  参考文献：
  名称：

  亚烷基双（过硫酸酯）：由（RC5H4）2TiS5制备的一类新的有机硫配体

  摘要：

  DOI：

  10.1021/om00081a026

文献信息

• Sulfur Compounds, 199. Novel Titanocene Thiolato Complexes and Their Application in Preparing New Sulfur‐Containing Heterocycles
  作者：Ralf Steudel、Monika Kustos、Vera Münchow、Ursula Westphal

  DOI：10.1002/cber.19971300614

  日期：1997.6

  Treatment of Cp2Ti(CO)2 (3) with the di- and polysulfanes 1,2,4-(CH2)2S3, C4S6 (9), C,7H10S3 (11), 1,2,4,6-(CH2)3S4 (16), C6H10S6(19), and S6 affords the titanocene chelate complexes Cp2TiS3(CH2)2 (8), (Cp2Ti)2C4S6 (10), Cp2TiS3C7H10 (13), Cp2TiS2C7H10 (14), Cp2TiS4(CH2)3 (17), Cp,2TiS6C6H6H10 (20), and Cp2TiS8 (23). 14 is also obtained from Cp2TiCl2 (1) and the geminal dithiol of norbornene. The analogous

  用二，1,2,4-（CH 2）2 S 3，C 4 S 6（9），C，7 H 10 S 3（11）和二硫醚处理Cp 2 Ti（CO）2（3） ，1,2,4,6-（CH 2）3 S 4（16），C 6 H 10 S 6（19）和S 6可提供钛茂螯合物Cp 2 TiS 3（CH 2）2（8），（Cp 2 Ti）2 C 4 S 6（10），Cp 2 TiS 3 C 7 H 10（13），Cp 2 TiS 2 C 7 H 10（14），Cp 2 TiS 4（CH 2）3（17），Cp，2 TiS 6 C 6 H 6 H 10（20）和Cp 2TiS 8（23）。还从Cp 2 TiCl 2（1）和降冰片烯的双生二硫醇获得14。与二环戊二烯的二硫醇的类似反应产生Cp 2 TiS 2 C 10 H 12（15）。在配位体转移反应，8分发生反应在SCL 2，得到1,2,3,5- tetrathiane（25），10提供了9上反应有Cl
• Preparation of 17 Sulfur‐Rich Chain‐Like Thiaalkanes R−S _<i>x</i> −R′−S _<i>y</i> −R and R−S _<i>x</i> −R′−S _<i>y</i> −R′−S _<i>z</i> −R ( <i>x</i> , <i>y</i> , <i>z</i>  &gt; 2) from Titanocene Thiolate Complexes
  作者：Vera Münchow、Ralf Steudel

  DOI：10.1002/ejic.200300591

  日期：2004.2

  AbstractTwo novel Cp2Ti(Cl)S3R′S3Tr complexes have been prepared by reaction of the six‐membered metallacycles Cp2TiS4R′ (Cp = η5‐C5H5, R′ = CMe2, 1,1‐C6H10) with the sulfenyl chloride TrSCl (Tr = CPh3) at 20 °C. These complexes were treated with: (a) sulfenyl chlorides (RSCl or RSSCl) to obtain 11 new thiaalkanes of the type R−Sx−R′−Sy−R (R = Tr, 4‐ClC6H4, 2‐C10H7; x = 3, y > 2), or (b) with SO2Cl2, SCl2 or S2Cl2 to prepare six sulfur‐rich species of the type Tr−Sx−R′−Sy−R′−Sz−Tr (x, z = 3, y > 3), as well as Cp2TiCl2. The thiaalkanes decompose upon heating to give mixtures of various linear and cyclic polysulfanes R2Sn and R′Sm. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)