1,1-bis(tetramethylphospholyl)dicarbonylzirconium | 398142-75-1

• 英文名称: 1,1-bis(tetramethylphospholyl)dicarbonylzirconium
• CAS: 398142-75-1
• 化学式: C₁₈H₂₄O₂P₂Zr
• 分子量: 425.559
• InChiKey: FYWLLMMCVIACGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1-bis(tetramethylphospholyl)dichlorozirconium 、 一氧化碳 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 以82%的产率得到1,1-bis(tetramethylphospholyl)dicarbonylzirconium
  参考文献：
  名称：

  Generation and Trapping of a 1,1‘-Diphosphazirconocene

  摘要：

  The reduction of [(eta(5)-C4Me4P)(2)ZrCl2] (1) by magnesium in THF affords a transient octamethyl-1,1'-diphosphazirconocene which can be trapped by CO, bis(trimethylsilyl)acetylene, and 2-butyne to give the corresponding dicarbonyl 2, zirconacyclopropene 3, and zirconacyclopentadiene 4; all of these products have been characterized by X-ray analyses. An assessment of the,pi-basicity of the eta(5)-C4Me4P ligand has been made by several methods: (a) a comparison of the IR carbonyl stretching frequencies of 2 and of other dicarbonylzirconocene complexes, (b) a correlation of the C-13 NMR and IR data in 3 and in similar zirconacyclopropenes, and (c) an electrochemical study on 1. All these experiments confirm that the eta(5)-C4Me4P ligand is a poorer pi-base than the Cp ligand.

  DOI：

  10.1021/om010634u