PdCl(C6H2(CH2NMe2)2-2,6-(t-BuMe2SiO)-4) | 1070260-88-6

• 英文名称: PdCl(C6H2(CH2NMe2)2-2,6-(t-BuMe2SiO)-4)
• CAS: 1070260-88-6
• 化学式: C₁₈H₃₃ClN₂OPdSi
• 分子量: 463.431
• InChiKey: FWYIVJPTHIKZLT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  PdCl(C6H2(CH2NMe2)2-2,6-(t-BuMe2SiO)-4) 在 tetrabutylammonium fluoride 作用下， 以 四氢呋喃 为溶剂， 以50%的产率得到PdCl(C6H2(CH2NMe2)2-2,6-(OH)-4)
  参考文献：
  名称：

  Self-assembly of para-OH functionalized ECE-metalated pincer complexes

  摘要：

  Various para-OH functionalized ECE-pincer metal complexes [MX(ECE-OH)L-n] (ECE-OH = [C6H2(CH2E)(2)-2,6- OH-4] , E = NMe2, PPh2 and SPh) were synthesized. The X-ray crystal structures of neutral [PdCl(SCS-OH)], [PdCl(NCN-OH)], and cationic [Pd(PCP-OH)(MeCN)](BF4) are reported. The neutral halide complexes exhibit self-assembly to form polymeric chains via H-bonding involving the para-OH group as donors and the halide ligand on the metal as acceptors. Moreover, the halide ligand can be replaced by a monomeric aryloxy-O ligand leading to the formation of a covalently bonded dimer. The crystal structure of such a dimer derived from [PdI(NCN-OH)] is reported. Furthermore, these pincer-metal complexes were tethered through a carbamate linker to a siloxane functionality with the aim to be immobilized on a silica support. The crystal structure of a siloxane-functionalized [PtI(NCN-Z)] complex exemplifies how other H-bonding interactions not involving the metal-halide groupings can lead to polymeric networks as well. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.06.016
• 作为产物：
  描述：

  palladium diacetate 、 lithium chloride 、 3,5-bis[(dimethylamino)methyl]-4-(trimethylsilyl)phenyl tert-butyldimethylsilyl ether 以 甲醇 为溶剂， 以89%的产率得到PdCl(C6H2(CH2NMe2)2-2,6-(t-BuMe2SiO)-4)
  参考文献：
  名称：

  Self-assembly of para-OH functionalized ECE-metalated pincer complexes

  摘要：

  Various para-OH functionalized ECE-pincer metal complexes [MX(ECE-OH)L-n] (ECE-OH = [C6H2(CH2E)(2)-2,6- OH-4] , E = NMe2, PPh2 and SPh) were synthesized. The X-ray crystal structures of neutral [PdCl(SCS-OH)], [PdCl(NCN-OH)], and cationic [Pd(PCP-OH)(MeCN)](BF4) are reported. The neutral halide complexes exhibit self-assembly to form polymeric chains via H-bonding involving the para-OH group as donors and the halide ligand on the metal as acceptors. Moreover, the halide ligand can be replaced by a monomeric aryloxy-O ligand leading to the formation of a covalently bonded dimer. The crystal structure of such a dimer derived from [PdI(NCN-OH)] is reported. Furthermore, these pincer-metal complexes were tethered through a carbamate linker to a siloxane functionality with the aim to be immobilized on a silica support. The crystal structure of a siloxane-functionalized [PtI(NCN-Z)] complex exemplifies how other H-bonding interactions not involving the metal-halide groupings can lead to polymeric networks as well. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.06.016