三氧化二锑 | 14459-54-2

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 中文名称: 三氧化二锑
• 英文名称: antimony oxide trichloride
• CAS: 14459-54-2
• 化学式: Cl₃OSb
• 分子量: 244.108
• InChiKey: IPSJOBCXDQJMFB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  1.57
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  三氧化二锑 、 sodium fluoride 以 neat (no solvent) 为溶剂， 生成 antimony oxide trifluoride
  参考文献：
  名称：

  The gas-phase on-line formation of antimony oxide trihalides, SbOX3 where X=F and Cl and their identifications by infrared spectroscopy

  摘要：

  Antimony oxide trihalides, SbOX3 molecules, where X=F or Cl have been produced, by means of an on-line process, using antimony trichloride, SbOCl3 as starting material passed over heated silver oxide at 230 degrees C. The antimony oxide trichloride SbOCl3 formed is then reacted with sodium fluoride, NaF at 550 degrees C to produce antimony oxide trifluoride, SbOF3. The products have been characterized by the IR spectra of their vapors. Low resolution gas-phase Fourier transform infrared spectra show strong bands centered at 1272 and 1217 cm(-1), assigned to v(1)(a(1)), the O=Sb stretching fundamental of SbOF3 and SbOCl3, respectively. Both observed bands show typical PQR-type structure with a strong Q-head. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(00)00256-0
• 作为产物：
  描述：

  三氯化锑 、 silver(l) oxide 以 neat (no solvent) 为溶剂， 生成 三氧化二锑
  参考文献：
  名称：

  The gas-phase on-line formation of antimony oxide trihalides, SbOX3 where X=F and Cl and their identifications by infrared spectroscopy

  摘要：

  Antimony oxide trihalides, SbOX3 molecules, where X=F or Cl have been produced, by means of an on-line process, using antimony trichloride, SbOCl3 as starting material passed over heated silver oxide at 230 degrees C. The antimony oxide trichloride SbOCl3 formed is then reacted with sodium fluoride, NaF at 550 degrees C to produce antimony oxide trifluoride, SbOF3. The products have been characterized by the IR spectra of their vapors. Low resolution gas-phase Fourier transform infrared spectra show strong bands centered at 1272 and 1217 cm(-1), assigned to v(1)(a(1)), the O=Sb stretching fundamental of SbOF3 and SbOCl3, respectively. Both observed bands show typical PQR-type structure with a strong Q-head. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(00)00256-0