(η(5)-acetylcyclopentadienyl)((1,2,8,9-η)tricyclo[7.5.0.0(1,7)]tetradeca-1,8-diene)cobalt | 200119-16-0

• 英文名称: (η(5)-acetylcyclopentadienyl)((1,2,8,9-η)tricyclo[7.5.0.0(1,7)]tetradeca-1,8-diene)cobalt
• 英文别名: (1,2:8,9-η4-tricyclo[7.5.0.0(2,8)]tetradeca-1,8-diene)(1-carboxymethyl-η5-cyclopentadienyl)cobalt
• CAS: 200119-16-0
• 化学式: C₂₁H₂₇CoO
• 分子量: 354.438
• InChiKey: POLPKLKNXSQISA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η(5)-acetylcyclopentadienyl)((1,2,8,9-η)tricyclo[7.5.0.0(1,7)]tetradeca-1,8-diene)cobalt 在 水 、 氯磷酸二乙酯 、 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 水 为溶剂， 以28%的产率得到(η(5)-ethynylcyclopentadienyl)((1,2,8,9-η)tricyclo[7.5.0.0(1,7)]tetradeca-1,8-diene)cobalt
  参考文献：
  名称：

  Schimanke, Holger; Gleiter, Rolf, Organometallics, 1998, vol. 17, p. 275 - 277

  摘要：

  DOI：
• 作为产物：
  描述：

  Co(η5-C5H4MeCO)(cod) 、 1,8-环十四二炔 以 further solvent(s) 为溶剂， 以22%的产率得到(η(5)-acetylcyclopentadienyl)((1,2,8,9-η)tricyclo[7.5.0.0(1,7)]tetradeca-1,8-diene)cobalt
  参考文献：
  名称：

  Schimanke, Holger; Gleiter, Rolf, Organometallics, 1998, vol. 17, p. 275 - 277

  摘要：

  DOI：

文献信息

• Transannular Interactions in Mixed Superphanes with One Thiophene and One CpCo-Stabilized Cyclobutadiene Ring:  Syntheses, Structures, and Electrochemistry
  作者：Silke Gath、Rolf Gleiter、Frank Rominger、Christian Bleiholder

  DOI：10.1021/om0608206

  日期：2007.1.1

  Superphanes consisting of one thiophene ring and various substituted RCo-stabilized cyclobutadiene (CBD) rings (R = Cp, C5H4(CH3), C-5(CH3)(5), C5H4(Si(CH3)(3)), C5H4(COCH3), 8-12) and one superphane with one thiophene ring and one CpCo-stabilized cyclopentadienone ring (13) were synthesized. The starting point was a tricyclic diyne with a central thiophene ring and two condensed 4-cyclodecynes, 19. Heating of 19 with RCo(COD) yielded 8-12, whereas the heating of 19 with CpCo(CO)(2) gave 13. X-ray structural investigation of 8-13 afforded the geometrical parameters in the solid state. Cyclic voltammetry showed a strong interaction between the thiophene ring and the CpCo-stabilized cyclobutadiene part. This interaction was substantiated by comparison between the CV data of 8-12 and model systems containing only the CpCo(CBD) part.