1-nitropyridinium tetrafluoroborate | 2375-72-6

• 英文名称: 1-nitropyridinium tetrafluoroborate
• 英文别名: N-nitropyridinium tetrafluoroborate
• CAS: 2375-72-6
• 化学式: BF₄*C₅H₅N₂O₂
• 分子量: 211.912
• InChiKey: QUSMALDKLXBOPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1-nitropyridinium tetrafluoroborate 在 KN₃O₄ 作用下， 以 乙腈 为溶剂， 以18%的产率得到N-nitropyridinium dinitramidate
  参考文献：
  名称：

  Dinitramide and its salts

  摘要：

  The methods for preparation and the properties of dinitramide salts with ammonia, hydrazine, hydroxylamine, formamidine, their alkylated and aminated derivatives, etc. are described.

  DOI：

  10.1007/bf00696969
• 作为试剂：
  描述：

  萘 在 1-nitropyridinium tetrafluoroborate 作用下， 以 乙腈 为溶剂， 反应 10.0h， 生成 硝基萘 、 2-硝基萘
  参考文献：
  名称：

  Kim, Eun K.; Bockman, T. Michael; Kochi, Jay K., Journal of the Chemical Society. Perkin transactions II, 1992, # 11, p. 1879 - 1891

  摘要：

  DOI：

文献信息

• Sankararaman, S.; Kochi, J. K., Journal of the Chemical Society. Perkin transactions II, 1991, # 1, p. 1 - 12
  作者：Sankararaman, S.、Kochi, J. K.

  DOI：——

  日期：——
• Bimetallic Reactivity. One-site Addition Two-metal Oxidation Reactions Using a Di-Co(II) Complex of a Binucleating Ligand with 5- and 6-Coordinate Sites
  作者：Christopher Incarvito、Arnold L. Rheingold、Anna L. Gavrilova、C. Jin Qin、B. Bosnich

  DOI：10.1021/ic010235r

  日期：2001.8.1

  The preparation of an unsymmetrical binucleating ligand bearing a bridging oxadiazole ring flanked on one side by three ligands and on the other by four ligands is described. When bound to two metals, the ligand forms complexes where the metals are in 5- and 6-coordinate sites after the incorporation of an exogenous bridging ligand. A di-Co2+ complex of th is ligand has been prepared containing a hydroxide bridge. The complex is readily oxidized to the di-Co3+ state by outer sphere electron transfer with ferrocenium ions. Addition of Br-2 or NO2+ to the di-Co2+ complex leads to the rapid formation of the di-Co3+ bromo or nitro complexes, respectively. The ligand characteristics which allow for double oxidation with ferrocenium ions and for the one-site addition two-metal oxidations with Br-2 and NO2+ are discussed in terms of mechanical coupling between the two metal sites.
• Bockman, T. M.; Kim, E. K.; Kochi, J. K., Bulletin de la Societe Chimique de France, 1993, vol. 130, # 3, p. 323 - 335
  作者：Bockman, T. M.、Kim, E. K.、Kochi, J. K.

  DOI：——

  日期：——