| 510709-39-4

• CAS: 510709-39-4
• 化学式: C₂₀H₃₃ClO₃SiTi
• 分子量: 432.899
• InChiKey: ZITMXGJBEIMOBS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dicobalt octacarbonyl 、 在 Hg-Na 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Preparation of Ti(IV), Zr(IV) and Sn(IV) metal alkyls containing the (PriO)3SiCH2 fragment

  摘要：

  By reaction of RMgCl (R = (Pr'O)(3)SiCH2) with CP2TiCl2, CP2ZrCl2 and SnCl4, the stable metal alkyls CP2TiClR (1), Cp2TiR2, Cp2ZrR2 and SnR4 were obtained in high yield and characterized. The reactivity of 1 towards [Cu(CH3CN)(4)]PF6 (as Cl abstractor) was investigated and compared to previously reported cases. Cp2TiF2 was obtained quantitatively. By reaction of 1 with NaCO(CO)(4) the compound Cp2RTi-O-TiClCp2 (2) was separated in very low yield. The crystal structures of 1 and 2 were also determined by X-ray diffraction methods. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01879-x
• 作为产物：
  描述：

  二氯二茂钛 、 triisopropoxysilylmethylmagnesium chloride 以 四氢呋喃 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Preparation of Ti(IV), Zr(IV) and Sn(IV) metal alkyls containing the (PriO)3SiCH2 fragment

  摘要：

  By reaction of RMgCl (R = (Pr'O)(3)SiCH2) with CP2TiCl2, CP2ZrCl2 and SnCl4, the stable metal alkyls CP2TiClR (1), Cp2TiR2, Cp2ZrR2 and SnR4 were obtained in high yield and characterized. The reactivity of 1 towards [Cu(CH3CN)(4)]PF6 (as Cl abstractor) was investigated and compared to previously reported cases. Cp2TiF2 was obtained quantitatively. By reaction of 1 with NaCO(CO)(4) the compound Cp2RTi-O-TiClCp2 (2) was separated in very low yield. The crystal structures of 1 and 2 were also determined by X-ray diffraction methods. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01879-x