bis[3,5-dinitro-4-chlorophenylcarboxylate]tetra-n-butyldistannoxane | 930096-15-4

• 英文名称: bis[3,5-dinitro-4-chlorophenylcarboxylate]tetra-n-butyldistannoxane
• CAS: 930096-15-4；1306700-65-1
• 化学式: C₆₀H₈₀Cl₄N₈O₂₆Sn₄
• 分子量: 1945.99
• InChiKey: FYDHQDBTKBDRMA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二丁基二氯化锡 、 4-氯-3,5-二硝基苯甲酸 以93%的产率得到bis[3,5-dinitro-4-chlorophenylcarboxylate]tetra-n-butyldistannoxane
  参考文献：
  名称：

  Self-assembled pentagonal bipyramidal and skew trapezoidal organotin(IV) complexes of substituted benzoic acids: Their antibacterial, antifungal, cytotoxic, insecticidal and urease inhibition activities

  摘要：

  Fourteen di- and triorganotin(IV) derivatives with pentagonal bipyramidal and skew trapezoidal geometries have been synthesized and characterized. Dimethylstannyl bis[3-amino-4-chlorophenylcarboxylate] (1), bis[3-amino-4-chlorophenylcarboxylato] tetraethyldistannoxane] (2) and bis[3,5-dinitro-4-chlorophenylcarboxylato] tetra-n-butyldistannoxane (10) are dinuclear and tetranuclear complexes of bidentate ligands. The crystal structure of (1) is dimeric in which each Sn atom is seven coordinated. Study of weak intramolecular Sn center dot center dot center dot O interactions is very important to decide geometry around tin. Furthermore, it has been investigated that these compounds exhibit fairly good antibacterial, antifungal, cytotoxic, insecticidal and antiurease activities. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.007