[Ru2(1,2-bis(2,2'-bipyridyl-6-yl)ethyne)(p-cumene)2(chloride)2](2+) | 1346417-48-8

• 英文名称: [Ru2(1,2-bis(2,2'-bipyridyl-6-yl)ethyne)(p-cumene)2(chloride)2](2+)
• 英文别名: [Ru2(C5H4NC5H3NCCC5H3NC5H4N)(MeC6H4Pr-i)2Cl2](2+)
• CAS: 1346417-48-8
• 化学式: C₄₂H₄₂Cl₂N₄Ru₂
• 分子量: 875.868
• InChiKey: TUXVZIQJNRPMHK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 1,2-bis(2,2’-bipyridyl-6-yl)ethyne 以 not given 为溶剂， 生成 [Ru2(1,2-bis(2,2'-bipyridyl-6-yl)ethyne)(p-cumene)2(chloride)2](2+)
  参考文献：
  名称：

  Photocatalytic Splitting of CS₂ to S₈ and a Carbon–Sulfur Polymer Catalyzed by a Bimetallic Ruthenium(II) Compound with a Tertiary Amine Binding Site: Toward Photocatalytic Splitting of CO₂?

  摘要：

  The catalytic photocleavage of CS2 to S-8 and a (CxSy)(n) polymer with visible light using a dinuclear ruthenium(II) compound with a bipyridine units for photoactivity and a vicinal tertiary amine binding site for CS2 activation was studied. The catalyst was characterized by X-ray diffraction, H-1 NMR, and C-13 NMR, ESI-MS and elemental analysis. CS2 photocleavage was significant (240 turnovers, 20 h) to yield isolable S-8 and a (CxSy)(n) polymer. A mononuclear catalyst or one without an amine binding site showed significantly less activity. XPS of the (CxSy)(n) polymer showed a carbon/sulfur ratio similar to 1.5-1.6 indicating that in part both C-S bonds of CS2 had been cleaved. Catalyst was also included within the polymer. The absence of peaks in the H-1 NMR verified the (CxSy)(n) nature of the polymer, while C-13 NMR and IR indicated that the polymer had multiple types of C-S and C-C bonds.

  DOI：

  10.1021/ic2008045
• 作为试剂：
  描述：

  二硫化碳 在 [Ru2(1,2-bis(2,2'-bipyridyl-6-yl)ethyne)(p-cumene)2(chloride)2](2+) 作用下， 以 四氢呋喃 、 水 为溶剂， 以3.9%的产率得到1,2,3,4,5,6,7,8-八硫杂环辛烷
  参考文献：
  名称：

  Photocatalytic Splitting of CS₂ to S₈ and a Carbon–Sulfur Polymer Catalyzed by a Bimetallic Ruthenium(II) Compound with a Tertiary Amine Binding Site: Toward Photocatalytic Splitting of CO₂?

  摘要：

  The catalytic photocleavage of CS2 to S-8 and a (CxSy)(n) polymer with visible light using a dinuclear ruthenium(II) compound with a bipyridine units for photoactivity and a vicinal tertiary amine binding site for CS2 activation was studied. The catalyst was characterized by X-ray diffraction, H-1 NMR, and C-13 NMR, ESI-MS and elemental analysis. CS2 photocleavage was significant (240 turnovers, 20 h) to yield isolable S-8 and a (CxSy)(n) polymer. A mononuclear catalyst or one without an amine binding site showed significantly less activity. XPS of the (CxSy)(n) polymer showed a carbon/sulfur ratio similar to 1.5-1.6 indicating that in part both C-S bonds of CS2 had been cleaved. Catalyst was also included within the polymer. The absence of peaks in the H-1 NMR verified the (CxSy)(n) nature of the polymer, while C-13 NMR and IR indicated that the polymer had multiple types of C-S and C-C bonds.

  DOI：

  10.1021/ic2008045