[(C5Me5)Ru(η6-N,N'-dimethylbenzimidazolium)](PF6)(SO3CF3) | 1311435-30-9

• 英文名称: [(C5Me5)Ru(η6-N,N'-dimethylbenzimidazolium)](PF6)(SO3CF3)
• CAS: 1311435-30-9
• 化学式: CF₃O₃S*C₁₉H₂₆N₂Ru*F₆P
• 分子量: 677.533
• InChiKey: VJRAETVGSNLBDH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Cp*Ru(CH3CN)3]OTf 、 1,3-二异丙基苯并咪唑四苯基硼酸盐 以 四氢呋喃 为溶剂， 以94%的产率得到[(C5Me5)Ru(η6-N,N'-dimethylbenzimidazolium)](PF6)(SO3CF3)
  参考文献：
  名称：

  A Cationic N-Heterocyclic Carbene with an Organometallic Backbone: Synthesis and Reactivity

  摘要：

  A new type of cationic N-heterocyclic carbene ligand has been developed by attachment of a cationic organometallic [(CsMes)Ru](+) fragment to a benzimidazolium cation and subsequent deprotonation of the dicationic sandwich complex. The coordination chemistry and electronic properties of the new carbene were investigated by experimental and theoretical methods.

  DOI：

  10.1021/om2004496