[[κP,η(2)(P=C)-(1-(2-diphenylphosphinoethyl)-diphenylphosphonio)-3-triphenylphosphonio-benzo[c]phospholide](η(5)-cyclopentadienyl)cobalt(I)] tetraphenyl borate | 375396-74-0

• 英文名称: [[κP,η(2)(P=C)-(1-(2-diphenylphosphinoethyl)-diphenylphosphonio)-3-triphenylphosphonio-benzo[c]phospholide](η(5)-cyclopentadienyl)cobalt(I)] tetraphenyl borate
• CAS: 375396-74-0
• 化学式: C₂₄H₂₀B*C₅₇H₄₈CoP₄
• 分子量: 1235.13
• InChiKey: XSMVOQFHNLGJGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  carbon monoxide,cobalt,cyclopenta-1,3-diene 、 [[κP,η(2)(P=C)-(1-(2-diphenylphosphinoethyl)-diphenylphosphonio)-3-triphenylphosphonio-benzo[c]phospholide](η(5)-cyclopentadienyl)cobalt(I)] tetraphenyl borate 以 四氢呋喃 为溶剂， 生成 一氧化碳
  参考文献：
  名称：

  η2(π)-双膦基苯并磷酯阳离子的配位：一种新的不饱和磷杂环络合模式

  摘要：

  The bis-phosphonio-benzo[c]phospholide tetraphenylborate 4[BPh4] reacts with CpCo(C2H4)(2) to form a chelate complex [Co(eta (5)-Cp)(kappa P-2,eta (2) (P=C)-4)][BPh4] (6[Bph(4)]) which was characterized by means of spectroscopic techniques and a single crystal X-ray diffraction study. The observed eta (2)(pi)-coordination of the benzophospholide moiety in the cation 6 is highly unusual for aromatic phosphorus heterocycles. The structural data suggest a pronounced coordination-induced localization of pi -electrons in the condensed ring system.

  DOI：

  10.1002/1521-3749(200109)627:9<2269::aid-zaac2269>3.0.co;2-i
• 作为产物：
  描述：

  η5-cyclopentadienylbis(ethene)cobalt 、 [1-[(2-diphenylphosphinoethyl)-diphenylphosphonio]-3-triphenylphosphonio-benzo[c]phospholide] tetraphenylborate 以 四氢呋喃 为溶剂， 以90%的产率得到[[κP,η(2)(P=C)-(1-(2-diphenylphosphinoethyl)-diphenylphosphonio)-3-triphenylphosphonio-benzo[c]phospholide](η(5)-cyclopentadienyl)cobalt(I)] tetraphenyl borate
  参考文献：
  名称：

  η2(π)-双膦基苯并磷酯阳离子的配位：一种新的不饱和磷杂环络合模式

  摘要：

  The bis-phosphonio-benzo[c]phospholide tetraphenylborate 4[BPh4] reacts with CpCo(C2H4)(2) to form a chelate complex [Co(eta (5)-Cp)(kappa P-2,eta (2) (P=C)-4)][BPh4] (6[Bph(4)]) which was characterized by means of spectroscopic techniques and a single crystal X-ray diffraction study. The observed eta (2)(pi)-coordination of the benzophospholide moiety in the cation 6 is highly unusual for aromatic phosphorus heterocycles. The structural data suggest a pronounced coordination-induced localization of pi -electrons in the condensed ring system.

  DOI：

  10.1002/1521-3749(200109)627:9<2269::aid-zaac2269>3.0.co;2-i